Synergistic effect of W(VI) and Ni(II) uptakes on an MgAl-layered double hydroxide.

IF 7.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Yili Xie, Xiujuan Yuan, Shichen Liu, Sili Ren, Wuhui Luo
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引用次数: 0

Abstract

The coadsorption of anionic and cationic pollutants on adsorbents holds considerable importance in the development of relevant removal technologies and the understanding of pollutant transport in complex environmental media. Herein, tungsten (W), an emerging contaminant, and nickel (Ni) were chosen as two differently charged inorganic pollutants to investigate their removal characteristics on a magnesium-aluminum layered double hydroxide (LDH) prepared via microwave radiation. In the single systems, the amount of adsorbed W on LDH was initially increased and then decreased with increasing initial W concentration. In concentrated W solutions, LDH dissolution was intensified, accompanied by the intercalation and polymerization of W in the interlayer space. Among the various oxyanions, phosphate showed the most substantial inhibition on W uptake. In contrast, uptake of Ni was enhanced with the rapider adsorption rate at higher concentrations, due to the isomorphic substitution and precipitation. Coexisting cations of similar sizes competed with Ni to substitute with Mg, resulting in reduced uptake, except in the case of Fe3+ which disintegrated the LDH structure. In a binary system, the uptakes of W and Ni increased by 2.65 and 1.80 times, respectively, compared to their corresponding single systems, indicating an intriguing synergistic effect. Furthermore, the presence of Ni restored the LDH's ability to remove W in the presence of coexisting H2PO4-, SO42-, and CrO42-. However, due to the presence of W, the coexisting Co2+ and Zn2+ inhibited Ni uptake more significantly. The crystallinity decrease of LDH was induced and identified as the cause of the uptake synergy between W and Ni. These findings provide valuable insights for the development of efficient multifunctional adsorbents and enhance our understanding of the transfer dynamics of W in the presence of coexisting substances.

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来源期刊
Environmental Research
Environmental Research 环境科学-公共卫生、环境卫生与职业卫生
CiteScore
12.60
自引率
8.40%
发文量
2480
审稿时长
4.7 months
期刊介绍: The Environmental Research journal presents a broad range of interdisciplinary research, focused on addressing worldwide environmental concerns and featuring innovative findings. Our publication strives to explore relevant anthropogenic issues across various environmental sectors, showcasing practical applications in real-life settings.
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