Columnar cobalt molybdate spinel rooted on three-dimensional nickel foam as robust catalyst for 4-nitrophenol degradation through peroxymonosulfate activation.

IF 7.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Jieling Huang, Qiulin Li, Yuyue Zhu, Jie Wu, Guangyin Fan
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引用次数: 0

Abstract

Metal oxides-catalyzed peroxymonosulfate (PMS) activation systems show promise in decomposing organic pollutants, whereas the critical challenges such as catalyst aggregation and metal ion leaching significantly impact the stability and reusability of catalysts and thus limit widespread application. To address these issues, an effective self-supported three-dimensional PMS activator consisted of spinel cobalt molybdate (CoMoO4) and nickel foam (NF) (CoMoO4/NF) is fabricated through hydrothermal and annealing processes. The cooperative redox interaction between Co and Mo metal sites in CoMoO4/NF play a crucial role in efficiently activating PMS to degrade 4-nitrophenol (4-NP). Specifically, the CoMoO4/NF/PMS system achieves a 95% degradation rate for 4-NP within 35 min. Attributing to the unique columnar structure and strong connection between CoMoO4 and NF, the catalyst/PMS system maintains high efficiency after five cycles. Furthermore, the system demonstrates broad applicability for degrading various organic pollutants and resistance to interference from different pH levels, inorganic anions, and humic acid. This study proposes radical/non-radical degradation pathways by identifying active species and investigates the degradation mechanism and toxicity of intermediate products for 4-NP. These findings offer valuable insights for designing and synthesizing self-supported catalysts to eliminate pollutants through PMS activation.

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来源期刊
Environmental Research
Environmental Research 环境科学-公共卫生、环境卫生与职业卫生
CiteScore
12.60
自引率
8.40%
发文量
2480
审稿时长
4.7 months
期刊介绍: The Environmental Research journal presents a broad range of interdisciplinary research, focused on addressing worldwide environmental concerns and featuring innovative findings. Our publication strives to explore relevant anthropogenic issues across various environmental sectors, showcasing practical applications in real-life settings.
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