A novel electromagnetic wave absorption geopolymer originated from iron tailings and blast furnace slag

Abstract

In this work, a novel electromagnetic wave absorption geopolymer was created with efficient utilization of two solid wastes iron tailings and blast furnace slag, meanwhile the mechanism and impacts of iron tailings content, water–solid ratio and specimen thickness on their electromagnetic wave absorption and mechanical property were systematically investigated. It was found the pores, micro-cracks and unreacted particles in the specimens are benefitial for electromagnetic wave absorption but against to compressive strength, even though the compressive strength reaches 69.7 MPa with the iron tailings content 50% and water–solid ratio 0.4. The addition of iron tailings significantly enhances the electromagnetic wave absorption properties of the geopolymers, and increasing iron tailings content improves the number of pores, micro-cracks and the permeability of geopolymers. The electromagnetic wave absorption properties of the geopolymer initially increase and then decrease with the increase of specimen thickness and water–solid ratio. With an iron tailings content 70%, water–solid ratio 0.4 and thickness 30 mm, the effective absorption bandwidth (< -5 dB) was optimized to 10.44 GHz with a minimum reflection loss of −13.34 dB. A new mechanism for electromagnetic absorption in iron tailings has been proposed, in which the electromagnetic wave absorption of geopolymers is mainly dominated by magnetic loss and spatial propagation loss. This study provides higher competitiveness and comprehensive utilisation of iron tailings in the field of electromagnetic wave absorbing building materials, and has great potential for applications in military and other fields affected by high electromagnetic wave frequencies.