Quaternary ammonium salt functionalized copper phthalocyanine-graphene oxide hybrids for cocatalyst-free carbon dioxide cycloaddition

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Lingling Wang, Zhihua Feng, Qingqing Hou, Zhangting Dang, Yue Yu, Cui Yang, Bo Tang, Qiucheng Zhou, Xiufu Hua, Renbo Wei, Terence X. Liu
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引用次数: 0

Abstract

Chemical conversion of carbon dioxide (CO2) into high-value products not only enhances environmental sustainability but also presents economic benefits. The development of novel and effective catalysts is crucial for facilitating the conversion of CO2 and the synthesis of these chemicals. In this study, we present the preparation of an ionic liquid-functionalized graphene oxide and copper phthalocyanine (CuPc) hybrid (GO-CuPc-IL). This was achieved through the chemical grafting of phthalonitrile groups and quaternary ammonium salts onto graphene oxide (GO), followed by in situ polymerization with phloroglucinol triphenyldinitrile. This hybrid catalyst was employed to catalyze the cycloaddition reaction of CO2 with epoxides under mild conditions. A series of analytical techniques confirmed the successful synthesis of the GO-CuPc-IL. The presence of abundant hydrogen bond donor groups (urea groups), Lewis acidic sites (coordinated copper rings), phthalocyanine rings, and numerous ionic active sites within the GO-CuPc-IL significantly facilitated the activation of reactants, enabling an efficient cycloaddition reaction of CO2 and epoxides. Notably, with 3.0 wt% of GO-CuPc-IL, the reaction achieved a yield of 98% and a selectivity of 99% at 1.5 MPa CO2 and 100 °C for 8 h, along with remarkable stability and reusability. This innovative hybrid catalyst promotes the simultaneous adsorption and activation of CO2 and epoxide by immobilizing multiple functional groups on the catalyst support, providing new avenues for sustainable CO2 conversion.

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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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