Reshaping quinolines by single-electron-transfer-triggered dearomatization

IF 19.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2024-12-12 DOI:10.1016/j.chempr.2024.11.007

Yun-Peng Chu, Jiajia Ma

引用次数: 0

Abstract

In this issue of Chem, Prof. Shunsuke Chiba, Prof. Derek Pratt, and their colleagues report a groundbreaking study on the dearomative dimerization and skeletal rearrangement of quinolines under polysulfide anion photocatalysis. This work demonstrates a unique method for transforming quinolines into complex sp³-rich polyheterocycles and 4-(3-indolylmethyl)quinolines through a sequence of reactions initiated by single-electron transfer (SET).

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来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.