Ultra-Strong Ionogel Adhesives via in situ Microphase Separation

IF 18.5 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Yangyu Huang, Xiaoqing Ming, Zhe Tang, Guoqing Chen, Xiaozheng Duan, He Zhu, Shiping Zhu, Qi Zhang
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Abstract

Ionogels hold great promise due to their numerous charges and abundant polarities, which facilitate strong interfacial interactions with substrates. However, the plasticizing effect of ionic liquid weakens their mechanical properties, limiting the adhesive performance of ionogel adhesives. Developing high-strength ionogel adhesives, therefore, remains a significant challenge. In this work, an exceptional ionogel adhesive is achieved by copolymerizing methyl methacrylate (MMA) and acrylic acid (AA) in 1-ethyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imide (EMITFSI). The distinct solubilities of the polymers in this ionic liquid result in in situ microphase separation. This novel ionogel exhibits an ultrahigh adhesion strength, with a lap shear strength of 13.41 MPa on glass, surpassing most values reported to date. The remarkable properties of this ionogel are primarily attributed to microphase separation, which enhances adhesion through the arrangement of hydrogen bonds at the interface and improves cohesion by dissipating energy within the bulk. This study offers promising prospects for the design and application of high-performance ionogel adhesives.

Abstract Image

Abstract Image

通过原位微相分离的超强离子凝胶粘合剂
电离层凝胶由于其大量的电荷和丰富的极性,促进了与底物的强界面相互作用,因此具有很大的前景。但离子液体的塑化作用削弱了其力学性能,限制了离子凝胶胶粘剂的粘接性能。因此,开发高强度离子凝胶粘合剂仍然是一个重大挑战。在这项工作中,通过将甲基丙烯酸甲酯(MMA)和丙烯酸(AA)共聚在1-乙基-3-甲基咪唑双(三氟甲基磺酰基)亚胺(EMITFSI)中获得了一种特殊的离子凝胶粘合剂。聚合物在离子液体中的不同溶解度导致原位微相分离。这种新型离子凝胶具有超高的粘接强度,在玻璃上的剪切强度为13.41 MPa,超过了迄今为止报道的大多数数值。这种离子凝胶的显著性能主要归功于微相分离,微相分离通过在界面上排列氢键来增强附着力,并通过在体内耗散能量来提高内聚力。本研究为高性能离子凝胶胶粘剂的设计和应用提供了广阔的前景。
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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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1-hydroxycyclohexyl phenyl ketone
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