Strong Acid‐free Homogeneous Catalytic Systems for the Ester Products Synthesis by Alkenes Alkoxycarbonylation: Recent Advances

IF 2.5 3区 化学 Q2 CHEMISTRY, ORGANIC
Nadezhda Tengizovna Sevostyanova, Sergey Alexandrovich Batashev
{"title":"Strong Acid‐free Homogeneous Catalytic Systems for the Ester Products Synthesis by Alkenes Alkoxycarbonylation: Recent Advances","authors":"Nadezhda Tengizovna Sevostyanova, Sergey Alexandrovich Batashev","doi":"10.1002/ejoc.202401010","DOIUrl":null,"url":null,"abstract":"Alkoxycarbonylation represents a method for the ester products synthesis from available reagents – unsaturated compounds, alcohols, and CO. The beginning of research on this reaction was laid in W. Reppe’ works in 1953. In early works, halides and carbonyls of Co, Ni, Rh, and Ir were used as catalysts, and alkoxycarbonylation was often complicated by the unsaturated compounds hydroformylation or alcohol carbonylation. In recent decades, in the presence of the most active and selective Pd‐phosphine systems with strong protonic acids, the products are typically only isomeric esters, which corresponds to the creating waste‐free production principles. At present, a large‐capacity synthesis process for methyl methacrylate, dubbed Alpha, is in operation, with the initial stage being ethylene methoxycarbonylation. In light of these developments, there is a growing interest among chemists and technologists in alkenes alkoxycarbonylation. The use of strong protonic acids as co‐catalysts is essential for the formation of active catalytic complexes. However, these acids are highly corrosive and can cause the alkenes isomerisation. This review is devoted to the analysis of acid‐free homogeneous Pd‐, Ru‐, Co‐, and Ni‐catalysts employed in alkenes alkoxycarbonylation over the past 15 years. As a result, polymers, monomers and other valuable linear and branched esters were obtained.","PeriodicalId":167,"journal":{"name":"European Journal of Organic Chemistry","volume":"15 1 1","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/ejoc.202401010","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

Abstract

Alkoxycarbonylation represents a method for the ester products synthesis from available reagents – unsaturated compounds, alcohols, and CO. The beginning of research on this reaction was laid in W. Reppe’ works in 1953. In early works, halides and carbonyls of Co, Ni, Rh, and Ir were used as catalysts, and alkoxycarbonylation was often complicated by the unsaturated compounds hydroformylation or alcohol carbonylation. In recent decades, in the presence of the most active and selective Pd‐phosphine systems with strong protonic acids, the products are typically only isomeric esters, which corresponds to the creating waste‐free production principles. At present, a large‐capacity synthesis process for methyl methacrylate, dubbed Alpha, is in operation, with the initial stage being ethylene methoxycarbonylation. In light of these developments, there is a growing interest among chemists and technologists in alkenes alkoxycarbonylation. The use of strong protonic acids as co‐catalysts is essential for the formation of active catalytic complexes. However, these acids are highly corrosive and can cause the alkenes isomerisation. This review is devoted to the analysis of acid‐free homogeneous Pd‐, Ru‐, Co‐, and Ni‐catalysts employed in alkenes alkoxycarbonylation over the past 15 years. As a result, polymers, monomers and other valuable linear and branched esters were obtained.
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信