Improved electro-actuation of polydimethylsiloxane-based composite dielectric elastomer via constructing semi-interlocked dual-network

IF 4.1 2区 化学 Q2 POLYMER SCIENCE
Liming Jin, Chuying Zhang, Haotong Guo, Huiqin Wang, Jinbo Bai, Hang Zhao
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引用次数: 0

Abstract

Dielectric elastomer (DE) has a pivotal potential in various applications as a typical electro-active polymer. However, traditional DE materials often require high electric fields to achieve an excellent electro-actuated performance, which severely restricts their practical applicability. In this study, vinyl methyl silicone (VMQ) macromolecular chains are introduced as the highly-viscous plasticizer to reduce the elastic modulus of polydimethylsiloxane (PDMS)-based DE composites. The bisilane-modified TiO2 nanoparticles (mTO) that grafted by thiols and octadecane are incorporated to increase the dielectric constant of DE composites. The synergistic effects contributed by these components give rise to a notable improvement in the electro-actuated performance of DE composites. Moreover, the thiol-ene click chemical reaction between the functional groups on mTO and VMQ makes the formation of a semi-interlocked cross-linked network structure within the PDMS-based elastomers. This network effectively mitigates the issue of plasticizer leaching during the long-term utilization of DE composites. The PDMS-based composite comprising 10 wt% mTO and 20 wt% VMQ achieves a remarkable electro-actuated strain of 72.5% at 65.4 V/μm, representing a 539% increase compared to pure PDMS (∼18.6%). This study provides an effective strategy for developing advanced DE composites with high electro-actuated properties at low electric fields.

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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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