David Berstad, Ingrid Snustad, Stian Traedal, Donghoi Kim, Jacob Stang
{"title":"Low-Temperature Phase Separation of CO2 from Syngas Mixtures─Experimental Results","authors":"David Berstad, Ingrid Snustad, Stian Traedal, Donghoi Kim, Jacob Stang","doi":"10.1021/acs.iecr.4c02522","DOIUrl":null,"url":null,"abstract":"To mitigate the increasing anthropogenic CO<sub>2</sub> emissions, hydrogen is pointed to as a potential low-emission alternative fuel for a range of applications. Gray hydrogen from natural gas reforming is the dominant industrial hydrogen source globally. If CO<sub>2</sub> capture and storage can be added with minimal efficiency reductions, blue hydrogen can reduce the carbon footprint drastically. A novel technology option for blue hydrogen production, is the use of proton conducting membranes for hydrogen purification combined with low-temperature condensation and phase separation of CO<sub>2</sub> from the retentate gas. This work presents results from 15 experiments for low-temperature phase separation and purification of CO<sub>2</sub> from five-component mixtures representative for retentate and tail gas compositions. The experiments have been conducted with feed rates between 120 and 307 kg/h and with CO<sub>2</sub> feed fractions between 56 and 82 mol %. The main separator pressures and temperatures range between 40 and 70 bar, and −55 and −45 °C, respectively. Final CO<sub>2</sub> product purities up to 99.90 mol % have been measured. The purity can be controlled through the pressure level in the flash purification separator and the temperature upstream of the inlet throttling valve. Experiments and corresponding predictions based on GERG-2008 and Peng–Robinson are generally consistent.","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"97 1","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial & Engineering Chemistry Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1021/acs.iecr.4c02522","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
To mitigate the increasing anthropogenic CO2 emissions, hydrogen is pointed to as a potential low-emission alternative fuel for a range of applications. Gray hydrogen from natural gas reforming is the dominant industrial hydrogen source globally. If CO2 capture and storage can be added with minimal efficiency reductions, blue hydrogen can reduce the carbon footprint drastically. A novel technology option for blue hydrogen production, is the use of proton conducting membranes for hydrogen purification combined with low-temperature condensation and phase separation of CO2 from the retentate gas. This work presents results from 15 experiments for low-temperature phase separation and purification of CO2 from five-component mixtures representative for retentate and tail gas compositions. The experiments have been conducted with feed rates between 120 and 307 kg/h and with CO2 feed fractions between 56 and 82 mol %. The main separator pressures and temperatures range between 40 and 70 bar, and −55 and −45 °C, respectively. Final CO2 product purities up to 99.90 mol % have been measured. The purity can be controlled through the pressure level in the flash purification separator and the temperature upstream of the inlet throttling valve. Experiments and corresponding predictions based on GERG-2008 and Peng–Robinson are generally consistent.
期刊介绍:
ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.