Quasi-one-dimensional alternating spin-1/2 antiferromagnetism in perovskite metal formate framework [(NH2)2CH]Cu(HCOO)3.

IF 2.3 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER
Ying Li, Jie Wang, Yuke Li, Hanjie Guo, Xing-Liang Xu, Xing'ao Li
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引用次数: 0

Abstract

The formamidinium copper formate [(NH2)2CH]Cu(HCOO)3(FMD-Cu) with a perovskite-like structure based on a nonporous metal-organic framework (MOF), is presented for its synthesis and magnetic properties. The magnetic properties and their couplings to the structure are derived from detailed magnetic susceptibility and heat capacity measurements. We also discuss the spin exchange couplings based on density functional theory (DFT) calculations. As a result, FMD-Cu exhibits the unusual quasi-one-dimensional antiferromagnetic (AFM) characteristics with the Néel temperatureTN= 12.0 K and an intrachain coupling constantJ/kB≈ 76.3 K. We also estimate the effective interchain couplingJ*/kB≈ 4.24 K, suggesting that FMD-Cu is close to an ideal candidate for one-dimensional magnet. Furthermore, the heat capacity shows a transition to an antiferromagnetic ordering state appears aroundTN. Besides, the nonzero parameterγ= 0.089 J mol-1K-1obtained from the linear relationship,γT, to the low temperature-dependent zero-field heat capacity data, can be associated with the magnetic excitations in insulating quasi-one-dimensional AFM Heisenberg spin-1/2 chains. The experimental estimate and DFT calculations are entirely consistent with a model of FMD-Cu in which AFM exchange interactions originating from Jahn-Teller distortion of the Cu2+(3d9) ions, leaving a sublattice of coupled ferromagnetic (FM) chains. Hence, FMD-Cu is proposed as a canonical model of a quasi-one-dimensional Heisenberg spin-1/2 antiferromagnetic material.

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来源期刊
Journal of Physics: Condensed Matter
Journal of Physics: Condensed Matter 物理-物理:凝聚态物理
CiteScore
5.30
自引率
7.40%
发文量
1288
审稿时长
2.1 months
期刊介绍: Journal of Physics: Condensed Matter covers the whole of condensed matter physics including soft condensed matter and nanostructures. Papers may report experimental, theoretical and simulation studies. Note that papers must contain fundamental condensed matter science: papers reporting methods of materials preparation or properties of materials without novel condensed matter content will not be accepted.
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