{"title":"Interpolyelectrolyte Complexes of Amphiphilic Polymers: The Case when a Synthesis Sequence Affects Properties","authors":"P. A. Fetin, A. E. Minov, I. M. Zorin","doi":"10.1134/S0965545X24600856","DOIUrl":null,"url":null,"abstract":"<p>The feasibility is considered of targeted production of interpolyelectrolyte complexes (IPECs) with an ordered supramolecular structure by polymerization in the composition of various polyelectrolyte–colloid complexes, direct mixing of polyelectrolytes in solution, and an interfacial reaction of polyelectrolytes. Using scanning electron microscopy and small-angle X-ray scattering, differences in the structure of interpolyelectrolyte complexes due to synthesis have been demonstrated. Methods for synthesizing IPEC dispersions with a controlled particle radius and the stability of such dispersions to dissociation into individual components are discussed, as well as some practical aspects of their use including laboratory testing of application potential.</p>","PeriodicalId":738,"journal":{"name":"Polymer Science, Series A","volume":"66 3","pages":"297 - 305"},"PeriodicalIF":1.0000,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series A","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S0965545X24600856","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The feasibility is considered of targeted production of interpolyelectrolyte complexes (IPECs) with an ordered supramolecular structure by polymerization in the composition of various polyelectrolyte–colloid complexes, direct mixing of polyelectrolytes in solution, and an interfacial reaction of polyelectrolytes. Using scanning electron microscopy and small-angle X-ray scattering, differences in the structure of interpolyelectrolyte complexes due to synthesis have been demonstrated. Methods for synthesizing IPEC dispersions with a controlled particle radius and the stability of such dispersions to dissociation into individual components are discussed, as well as some practical aspects of their use including laboratory testing of application potential.
期刊介绍：
Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
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