Influence of Rolling Speed on the Mechanism of Adiabatic Shear Band Formation and Plastic Flow in Polyethylene Terephthalate Films

IF 1 4区 化学 Q4 POLYMER SCIENCE
S. L. Bazhenov, I. V. Sosnovskii, A. S. Kechek’yan, A. L. Volynskii
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引用次数: 0

Abstract

Amorphous polyethylene terephthalate was oriented by rolling at room temperature on laboratory rollers. During rolling, a system of shear bands appeared, which was observed using crossed polarizers. The effect of rolling speed and degree on the shear band system was studied. At low rolling speeds (6.5 mm/min), plastic flow occurs through numerous fine shear bands. At higher speeds (above 1300 mm/min), a single serrated deformation zone is observed. This is explained by thermal softening of the polymer and a decrease in yield strength, which suppresses the formation of competing shear bands. At intermediate rolling speeds, two, three, four, or five serrated zones appear, spaced approximately equally. Increasing the degree of rolling leads to an increase in the number of serrated shear zones and homogenization of the flow process. The temperature in the shear bands was estimated, and it was shown that very slight heating of the bands is sufficient to prevent the formation of multiple fine shear bands. A significant difference was noted between the adiabatic deformation of the sample and the adiabatic shear bands.

Abstract Image

轧制速度对聚对苯二甲酸乙二醇酯薄膜绝热剪切带形成和塑性流动机理的影响
室温下在实验室辊上轧制非晶态聚对苯二甲酸乙二醇酯取向。在轧制过程中,出现了一个剪切带系统,这是用交叉偏振镜观察到的。研究了轧制速度和轧制程度对剪切带系统的影响。在低轧制速度下(6.5 mm/min),塑性流动通过许多细剪切带发生。在较高的速度下(超过1300毫米/分钟),观察到一个单一的锯齿形变形区。这是由聚合物的热软化和屈服强度的降低来解释的,这抑制了竞争剪切带的形成。在中等轧制速度下,出现两个、三个、四个或五个锯齿区,它们的间距大致相等。随着轧制程度的增加,锯齿状剪切带的数量增加,流动过程均匀化。对剪切带内的温度进行了估计,结果表明,对剪切带进行轻微加热就足以防止形成多个细剪切带。试样的绝热变形与绝热剪切带之间存在显著差异。
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来源期刊
Polymer Science, Series A
Polymer Science, Series A 化学-高分子科学
CiteScore
1.70
自引率
0.00%
发文量
55
审稿时长
3 months
期刊介绍: Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
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