Effect of calcination temperature on the microstructure and electrochemical performance of NaFePO4/C cathode materials for sodium-ion battery

IF 2.8 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC
Chunmei Tang, Shuxin Liu, Jichuan Huo, Wei Ma, Jing Li, Ning Chen
{"title":"Effect of calcination temperature on the microstructure and electrochemical performance of NaFePO4/C cathode materials for sodium-ion battery","authors":"Chunmei Tang,&nbsp;Shuxin Liu,&nbsp;Jichuan Huo,&nbsp;Wei Ma,&nbsp;Jing Li,&nbsp;Ning Chen","doi":"10.1007/s10854-024-13986-3","DOIUrl":null,"url":null,"abstract":"<div><p>Among the various types of cathode materials for sodium-ion batteries, NaFePO<sub>4</sub> has attracted much attention due to its high theoretical capacity (155 mAh g<sup>−1</sup>), low cost, and high structural stability. However, the thermodynamically stable maricite form of NaFePO<sub>4</sub> is regarded as electrochemically inactive because of its closed framework, which lacks pathways for Na⁺ diffusion. While numerous modification techniques exist, many require substantial energy input. In this study, the NaFePO<sub>4</sub>/C cathode materials with amorphous and maricite phases were in situ constructed through an extremely simple sol–gel method at different calcination temperatures without incorporating other complicated technology. All of the microstructure, phase components, particle size, and specific surface of NaFePO<sub>4</sub>/C cathode materials were well controlled by this one-step method. Among them, the NaFePO<sub>4</sub>/C with amorphous and maricite phases calcined at 450 °C had an excellent electrochemical performance, the discharge specific capacity maintained at 123.6 mAh g<sup>−1</sup> after 10 cycles and becomes stable, and the capacity decay rate was only 4.00% after 100 cycles at 0.1 C at room temperature, Na<sup>+</sup> diffusion coefficient of 1.026 × 10<sup>–17</sup> cm<sup>2</sup> s<sup>−1</sup>, and charge transfer resistance of 998.6 Ω.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"35 35","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science: Materials in Electronics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10854-024-13986-3","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0

Abstract

Among the various types of cathode materials for sodium-ion batteries, NaFePO4 has attracted much attention due to its high theoretical capacity (155 mAh g−1), low cost, and high structural stability. However, the thermodynamically stable maricite form of NaFePO4 is regarded as electrochemically inactive because of its closed framework, which lacks pathways for Na⁺ diffusion. While numerous modification techniques exist, many require substantial energy input. In this study, the NaFePO4/C cathode materials with amorphous and maricite phases were in situ constructed through an extremely simple sol–gel method at different calcination temperatures without incorporating other complicated technology. All of the microstructure, phase components, particle size, and specific surface of NaFePO4/C cathode materials were well controlled by this one-step method. Among them, the NaFePO4/C with amorphous and maricite phases calcined at 450 °C had an excellent electrochemical performance, the discharge specific capacity maintained at 123.6 mAh g−1 after 10 cycles and becomes stable, and the capacity decay rate was only 4.00% after 100 cycles at 0.1 C at room temperature, Na+ diffusion coefficient of 1.026 × 10–17 cm2 s−1, and charge transfer resistance of 998.6 Ω.

煅烧温度对钠离子电池用NaFePO4/C正极材料微观结构和电化学性能的影响
在钠离子电池正极材料中,NaFePO4因其高理论容量(155 mAh g−1)、低成本和高结构稳定性而备受关注。然而,热力学稳定的海洋盐态NaFePO4被认为是电化学无活性的,因为它的封闭框架缺乏Na⁺扩散的途径。虽然存在许多修改技术,但许多技术需要大量的能量输入。在本研究中,在不同的煅烧温度下,通过极其简单的溶胶-凝胶法原位构建了非晶相和海硅酸盐相的NaFePO4/C正极材料,而无需采用其他复杂的工艺。该方法可以很好地控制NaFePO4/C正极材料的微观结构、相组成、粒径和比表面。其中,在450℃下煅烧的非晶相和海硅酸盐相NaFePO4/C具有优异的电化学性能,放电比容量在10次循环后保持在123.6 mAh g−1并趋于稳定,在室温0.1℃下循环100次后容量衰减率仅为4.00%,Na+扩散系数为1.026 × 10 - 17 cm2 s−1,电荷转移电阻为998.6 Ω。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Materials Science: Materials in Electronics
Journal of Materials Science: Materials in Electronics 工程技术-材料科学:综合
CiteScore
5.00
自引率
7.10%
发文量
1931
审稿时长
2 months
期刊介绍: The Journal of Materials Science: Materials in Electronics is an established refereed companion to the Journal of Materials Science. It publishes papers on materials and their applications in modern electronics, covering the ground between fundamental science, such as semiconductor physics, and work concerned specifically with applications. It explores the growth and preparation of new materials, as well as their processing, fabrication, bonding and encapsulation, together with the reliability, failure analysis, quality assurance and characterization related to the whole range of applications in electronics. The Journal presents papers in newly developing fields such as low dimensional structures and devices, optoelectronics including III-V compounds, glasses and linear/non-linear crystal materials and lasers, high Tc superconductors, conducting polymers, thick film materials and new contact technologies, as well as the established electronics device and circuit materials.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信