Reducing Lithium-Diffusion Barrier on the Wadsley–Roth Crystallographic Shear Plane via Low-Valent Cation Doping for Ultrahigh Power Lithium-Ion Batteries

IF 24.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Jun Ma, Yu Xiang, Jingyue Xu, Wenfeng Zhang, Huimin Zhang, Jingyi Qiu, Xiayu Zhu, Hao Zhang, Haiping Lin, Gaoping Cao
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引用次数: 0

Abstract

Rapid-charging niobium–tungsten oxide Nb14W3O44 (NbWO) anodes with a Wadsley–Roth crystallographic shear (WRCS) structure possess 3D interconnected open tunnels. However, the anisotropic Li+ diffusion paths lead to a high lithium-diffusion barrier of hooping between window sites across edge-shared octahedrons, as the rate-limiting step of hooping. To improve the rate capability of NbWO, doping it with low-valent cations (with valences lower than W6+) to reduce the high lithium-diffusion barrier is proposed. Electron energy loss spectroscopy reveals that low-valent V5+, V4+, Tb4+, and Ce4+ tend to distribute on the crystallographic shear plane under electrostatic repulsion forces. The reduction in steric hindrance resulting from the increased long bond length ratio of doped edge-shared octahedrons, coupled with coordination environment modification of [LiO5] on the crystallographic shear plane due to the low energy level of V5+, enhances Li+ diffusion kinetics and cyclic stability. V5+- and Tb4+-doped NbWOs achieve rate capacities of 83 and 63 mAh g−1, at 200 C (1C = 0.178 Ag−1) and retain 75.42% and 86.79% of their capacities, respectively, after 3700 cycles at 20 C. Thus, the proposed doping strategy is promising for preparing WRCS-type niobium-based oxides for ultrafast lithium storage.

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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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