Isolation and Characterization of the Dimetal Decacarbonyl Dication [Ru2(CO)10]2+ and the Metal-Only Lewis-Pair [Ag{Ru(CO)5}2]+

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-12-06 DOI:10.1039/d4dt03364g

Malte Sellin, Jörg Grunenberg, Ingo Krossing

引用次数: 0

Abstract

The reaction of Ag⁺ with Ru₃(CO)₁₂ in CO atmosphere under concommittant irradiation with UV-light yields a salt of the metal-only Lewis-pair [Ag{Ru(CO)₅}₂]⁺. Switching the silver cation for a more process-selective deelectronator yields a salt of the homo-leptic transition metal carbonyl cation [Ru₂(CO)₁₀]²⁺, which fills the gap between the known cations [Ru(CO)₆]²⁺ and [Ru₃(CO)₁₄]²⁺. The amount of π-backdonation in this series was studied by a combination of vibrational spectroscopy and computed relaxed force constants.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.