Isolation and characterization of the dimetal decacarbonyl dication [Ru2(CO)10]2+ and the metal-only Lewis-pair [Ag{Ru(CO)5}2]+ †

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-12-06 DOI:10.1039/D4DT03364G

Malte Sellin, Jörg Grunenberg and Ingo Krossing

引用次数: 0

Abstract

The reaction of Ag⁺ with Ru₃(CO)₁₂ in a CO atmosphere under concommittant irradiation with UV-light yields a salt of the metal-only Lewis-pair [Ag{Ru(CO)₅}₂]⁺. Switching the silver cation for a more process-selective deelectronator yields a salt of the homoleptic transition metal carbonyl cation [Ru₂(CO)₁₀]²⁺, which fills the gap between the known cations [Ru(CO)₆]²⁺ and [Ru₃(CO)₁₄]²⁺. The amount of π-backdonation in this series was studied by a combination of vibrational spectroscopy and computed relaxed force constants.

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二金属十羰基反应[Ru2(CO)10]2+和纯金属lewis对[Ag{Ru(CO)5}2]+的分离与表征

Ag+与Ru3(CO)12在CO气氛中，在紫外光的同步照射下反应生成一种纯金属路易斯对盐[Ag{Ru(CO)5}2]+。将银阳离子转换为更具工艺选择性的脱电子剂，产生了一种盐盐的同诱变过渡金属羰基阳离子[Ru2(CO)10]2+，填补了已知阳离子[Ru(CO)6]2+和[Ru3(CO)14]2+之间的空白。用振动谱法和计算松弛力常数相结合的方法研究了该系列中π-反给度的大小。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.