Existence of hydroxymethanesulfonate (HMS) during spring haze and sandstorm events in Beijing: Implications for a heterogeneous formation pathway on mineral aerosols

IF 7.6 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Yunzhi Xu , Tao Ma , Fengkui Duan , Shuxiao Wang , Jingkun Jiang , Yafang Cheng , Hang Su , Taicheng An , Yongliang Ma , Takashi Kimoto , Tao Huang , Kebin He
{"title":"Existence of hydroxymethanesulfonate (HMS) during spring haze and sandstorm events in Beijing: Implications for a heterogeneous formation pathway on mineral aerosols","authors":"Yunzhi Xu ,&nbsp;Tao Ma ,&nbsp;Fengkui Duan ,&nbsp;Shuxiao Wang ,&nbsp;Jingkun Jiang ,&nbsp;Yafang Cheng ,&nbsp;Hang Su ,&nbsp;Taicheng An ,&nbsp;Yongliang Ma ,&nbsp;Takashi Kimoto ,&nbsp;Tao Huang ,&nbsp;Kebin He","doi":"10.1016/j.envpol.2024.125483","DOIUrl":null,"url":null,"abstract":"<div><div>Hydroxymethylsulfonate (HMS) is an abundant secondary organic aerosol from aqueous or heterogeneous processes and may be misidentified as sulfate in conventional measurements. High concentrations of HMS have been observed in humid winter and autumn haze in northern China, while its prevalence in other seasons is unclear and the production medium is controversial. In this study, our field measurements in Beijing during the 2021 spring first showed the presence of HMS in PM<sub>2.5</sub> during both haze and sandstorm events despite the different atmospheric conditions. HMS accounted for 0.44% of PM<sub>2.5</sub> during haze periods, higher than the proportion (0.097%) during sandstorms. The sum of HMS and sulfate was also higher during the haze (6.5 μg m<sup>−3</sup>) than during the sandstorm (2.6 μg m<sup>−3</sup>), while the HMS/sulfate molar ratio during the haze (0.021) was similar to the value during the sandstorm (0.019). HMS concentration showed a good positive correlation with aerosol water content (AWC), indicating multiphase production. During haze periods, relatively high AWC favored the formation of HMS. In contrast, relative humidity and AWC decreased significantly during sandstorm events, while high pH favored HMS formation. In addition, higher concentrations and proportions of HMS were observed in PM<sub>2.5−10</sub> than in PM<sub>2.5</sub>. The presence of HMS in dust particles indicated a heterogeneous formation mechanism of HMS on mineral aerosols. Our findings broaden the prevalence of HMS in aerosols and indicate a new HMS formation mechanism from the perspective of observation.</div></div>","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":"366 ","pages":"Article 125483"},"PeriodicalIF":7.6000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Pollution","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0269749124022000","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0

Abstract

Hydroxymethylsulfonate (HMS) is an abundant secondary organic aerosol from aqueous or heterogeneous processes and may be misidentified as sulfate in conventional measurements. High concentrations of HMS have been observed in humid winter and autumn haze in northern China, while its prevalence in other seasons is unclear and the production medium is controversial. In this study, our field measurements in Beijing during the 2021 spring first showed the presence of HMS in PM2.5 during both haze and sandstorm events despite the different atmospheric conditions. HMS accounted for 0.44% of PM2.5 during haze periods, higher than the proportion (0.097%) during sandstorms. The sum of HMS and sulfate was also higher during the haze (6.5 μg m−3) than during the sandstorm (2.6 μg m−3), while the HMS/sulfate molar ratio during the haze (0.021) was similar to the value during the sandstorm (0.019). HMS concentration showed a good positive correlation with aerosol water content (AWC), indicating multiphase production. During haze periods, relatively high AWC favored the formation of HMS. In contrast, relative humidity and AWC decreased significantly during sandstorm events, while high pH favored HMS formation. In addition, higher concentrations and proportions of HMS were observed in PM2.5−10 than in PM2.5. The presence of HMS in dust particles indicated a heterogeneous formation mechanism of HMS on mineral aerosols. Our findings broaden the prevalence of HMS in aerosols and indicate a new HMS formation mechanism from the perspective of observation.

Abstract Image

Abstract Image

北京春季雾霾和沙尘暴事件中羟基甲烷磺酸盐(HMS)的存在:对矿物气溶胶非均质形成途径的影响
羟甲基磺酸(HMS)是一种丰富的二次有机气溶胶,从水或非均相过程中产生,在常规测量中可能被误认为硫酸盐。在中国北方潮湿的冬季和秋季雾霾中观察到高浓度的HMS,而其在其他季节的流行情况尚不清楚,生产介质也存在争议。在本研究中,我们于2021年春季在北京进行的实地测量首次显示,尽管大气条件不同,但在雾霾和沙尘暴事件期间PM2.5中都存在HMS。霾期HMS占PM2.5的0.44%,高于沙尘暴期的0.097%。霾期间HMS和硫酸盐的总和(6.5 μ m−3)高于沙尘暴期间(2.6 μ m−3),而霾期间HMS/硫酸盐的摩尔比(0.021)与沙尘暴期间(0.019)相近。HMS浓度与气溶胶含水量(AWC)呈良好的正相关,为多相生产。在霾期,较高的AWC有利于HMS的形成。相对湿度和AWC在沙尘暴期间显著降低,高pH有利于HMS的形成。此外,PM2.5−10中HMS的浓度和比例高于PM2.5。尘埃颗粒中HMS的存在表明HMS对矿物气溶胶的形成机制是不均匀的。我们的发现扩大了气溶胶中HMS的流行范围,并从观测的角度提出了一种新的HMS形成机制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Environmental Pollution
Environmental Pollution 环境科学-环境科学
CiteScore
16.00
自引率
6.70%
发文量
2082
审稿时长
2.9 months
期刊介绍: Environmental Pollution is an international peer-reviewed journal that publishes high-quality research papers and review articles covering all aspects of environmental pollution and its impacts on ecosystems and human health. Subject areas include, but are not limited to: • Sources and occurrences of pollutants that are clearly defined and measured in environmental compartments, food and food-related items, and human bodies; • Interlinks between contaminant exposure and biological, ecological, and human health effects, including those of climate change; • Contaminants of emerging concerns (including but not limited to antibiotic resistant microorganisms or genes, microplastics/nanoplastics, electronic wastes, light, and noise) and/or their biological, ecological, or human health effects; • Laboratory and field studies on the remediation/mitigation of environmental pollution via new techniques and with clear links to biological, ecological, or human health effects; • Modeling of pollution processes, patterns, or trends that is of clear environmental and/or human health interest; • New techniques that measure and examine environmental occurrences, transport, behavior, and effects of pollutants within the environment or the laboratory, provided that they can be clearly used to address problems within regional or global environmental compartments.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信