Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine
IF 1.7
4区 化学
Q3 CHEMISTRY, MULTIDISCIPLINARY
引用次数: 0
Abstract
Two new mixed-ligand 3d-metal (MnII, CuII) coordination compounds with diethylmalonate anions and 4,4′-bipyridine were synthesized and characterized by IR spectroscopy and X-ray diffraction. The complex [Mn(HEt2mal)2(bpy)(H2O)2]n (1) (H2Et2mal is diethylmalonic acid, bpy is 4,4′-bipyridine) contains six-coordinate metal atoms and has a chain structure. In the structure of complex 1, two interpenetrating frameworks are formed through hydrogen bonds. The coordination polymer {[Cu2(Et2mal)2(bpy)(H2O)]•6 H2O}n (2) contains four- and five-coordinate copper(ii) cations and forms infinite layers perpendicular to the crystallographic axis a.
含4,4′-联吡啶的二乙基丙二酸铜（ii）和锰（ii）的合成和结构
合成了两个新的与丙二酸二乙酯阴离子和4,4′-联吡啶混合配体的三维金属（MnII, CuII）配合物，并用红外光谱和x射线衍射对其进行了表征。配合物[Mn(HEt2mal)2(bpy)(H2O)2]n (1) （H2Et2mal为二乙基丙二酸，bpy为4,4′-联吡啶）含有六配位金属原子，具有链式结构。在配合物1的结构中，通过氢键形成两个互穿框架。配位聚合物{[Cu2(Et2mal)2(bpy)(H2O)]•6 H2O}n(2)含有四坐标和五坐标铜（ii）阳离子，并形成垂直于结晶轴a的无限层。
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来源期刊
Russian Chemical Bulletin
化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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