The use of NiI2 as a catalyst for CO2 addition to oxiranes: activation methods

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-12-06 DOI:10.1007/s11172-024-4426-0

S. E. Lyubimov, P. V. Cherkasova

引用次数: 0

Abstract

Nickel(ii) iodide with organic and inorganic additives was tested in the addition of CO₂ to oxiranes. The introduction of diethylamine leads to the formation of an effective catalyst, which is, in some cases, capable of completing the reaction in the presence of 1 mol.% NiI₂ over a period of 1 h.

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用NiI2作为催化剂对氧环烷进行CO2加成：活化方法

用有机和无机添加剂对碘化镍（ii）进行了在氧环烷中添加CO2的试验。二乙胺的引入导致有效催化剂的形成，在某些情况下，它能够在1mol .% NiI2存在的情况下在1h内完成反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.