Modification of blend reverse osmosis membranes using ZrO2 for desalination process purposes

IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES
Saleh O. Alaswad, Eman S. Mansor, Heba Abdallah, Ahmed M. Shaban
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Abstract

Desalination of water is a crucial step in the process of obtaining potable water. One of the main challenges for the researchers is its efficient application and affordable preparation. It was planned to prepare the flat sheet membranes using cellulose acetate as a base polymer, and polyvinyl alcohol (PVA) as an additive with dosing of (0.1, 0.3, 0.5, and 0.7 wt%) from zirconium oxide (ZrO2) nanoparticle. SEM, TEM, and XRD analyses were used to characterize the generated ZrO2 nanoparticle in order to confirm its nano-size and crystal structure. The surface morphologies and existence of the dense layer, which is the typical property of the RO membrane capable of salt separation, were identified on the manufactured RO membranes by SEM. Membranes prepared by embedding 0.5 wt%ZrO2 with PVA/CA proved efficient as RO membranes using 2000 ppm NaCl and exhibited high salt rejection of 97% and water permeability of 12.5 LMH. Also, there is a decrease in the NaCl removal tendency was observed with the excessive dosages of ZrO2 with 0.7 wt%, which was due to the concentration polarization, which blocks the pores on the surfaces of the membranes. The antifouling behavior of the prepared membranes was tested using bovine serum albumin (BSA), the results indicate the low irreversible resistance, total fouling resistance, and high flux recovery ratio compared to the neat membrane. The prepared membranes have a stable salt rejection and water productivity even after demonstrating with chlorine (25–100 mg l−1 of NaOCl for 120 min).

用ZrO2改性海水淡化共混反渗透膜
海水淡化是获取饮用水过程中的关键步骤。研究人员面临的主要挑战之一是其有效的应用和负担得起的制备。计划以醋酸纤维素为基础聚合物,聚乙烯醇(PVA)为添加剂,以氧化锆(ZrO2)纳米颗粒为原料,添加量分别为(0.1、0.3、0.5和0.7 wt%),制备平板膜。利用SEM、TEM和XRD等分析手段对合成的ZrO2纳米颗粒进行表征,以确定其纳米尺寸和晶体结构。通过扫描电镜对制备的反渗透膜的表面形貌和致密层的存在进行了表征,发现了反渗透膜具有典型的盐分离特性。用PVA/CA包埋0.5 wt%ZrO2制备的膜在2000 ppm NaCl条件下具有良好的反渗透性能,其除盐率高达97%,透水性为12.5 LMH。当ZrO2添加量为0.7 wt%时,NaCl去除率下降,这是由于ZrO2的浓度极化阻塞了膜表面的孔隙。用牛血清白蛋白(BSA)测试了制备的膜的防污性能,结果表明,与纯膜相比,制备的膜具有较低的不可逆阻力、总抗污能力和较高的通量回收率。制备的膜在氯(25-100 mg l - 1 NaOCl)作用120分钟后仍具有稳定的防盐性能和水生产力。
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来源期刊
Applied Water Science
Applied Water Science WATER RESOURCES-
CiteScore
9.90
自引率
3.60%
发文量
268
审稿时长
13 weeks
期刊介绍:
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