Bifenthrin's Environmental Fate: An Insight Into Its Soil Sorption and Degradation Studies.

IF 2.3 3区 化学 Q3 CHEMISTRY, ANALYTICAL
Journal of Analytical Methods in Chemistry Pub Date : 2024-11-25 eCollection Date: 2024-01-01 DOI:10.1155/jamc/8868954
Jehad S Al-Hawadi, Sara Majid, Khuram Shahzad Ahmad, Gaber E Eldesoky, Ghulam Abbas Ashraf
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引用次数: 0

Abstract

To fully comprehend each pesticide's behavior and interactions with soil and the environment, a thorough and nuanced analysis of each one is thought necessary. In this study, 10 randomly selected heterogeneous soil samples, each with distinct characteristics, were subjected to sorption trials as well as disintegration tests using biodegradation, hydrolysis, and photolysis. For sorption tests, the batch equilibrium approach was used, which revealed a dependence on the soils' physicochemical characteristics. Bifenthrin's distribution coefficient (K d ) varied from 7.27 to 25.89 μg·ml-1, with R 2 values varying from 0.92 to 0.99. Each soil physicochemical characteristic was associated with the various sorptive outcomes, which suggested an exothermic adsorptive reaction based on the negative thermodynamic values. The hydrolysis, soil-induced biodegradation, and photolysis processes had the shortest half-lives of bifenthrin, measuring 13.5 days, 12 days, and 121.5 days, respectively. According to these findings, bifenthrin has a moderate amount of binding and stability in soil, which makes partial decomposition of parent and daughter molecules challenging. This research advances our knowledge of bifenthrin's deteriorating processes and aids in the creation of cutting-edge strategies for ecological restoration using natural processes.

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来源期刊
Journal of Analytical Methods in Chemistry
Journal of Analytical Methods in Chemistry CHEMISTRY, ANALYTICAL-ENGINEERING, CIVIL
CiteScore
4.80
自引率
3.80%
发文量
79
审稿时长
6-12 weeks
期刊介绍: Journal of Analytical Methods in Chemistry publishes papers reporting methods and instrumentation for chemical analysis, and their application to real-world problems. Articles may be either practical or theoretical. Subject areas include (but are by no means limited to): Separation Spectroscopy Mass spectrometry Chromatography Analytical Sample Preparation Electrochemical analysis Hyphenated techniques Data processing As well as original research, Journal of Analytical Methods in Chemistry also publishes focused review articles that examine the state of the art, identify emerging trends, and suggest future directions for developing fields.
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