Economically Scalable Cu-based MOFs: Vital Role of Structural Integrity towards Selectivity on Azeotropic Ethanol Dehydration.

IF 3.9 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - A European Journal Pub Date : 2025-01-09 Epub Date: 2024-12-12 DOI:10.1002/chem.202402509

Yollada Inchongkol, Kanyaporn Adpakpang, Panyapat Ponchai, Thassanant Atithep, Nattamon Chitterisin, Somlak Ittisanronnachai, Teera Butburee, Sareeya Bureekaew

引用次数: 0

Abstract

A facile, green, and economical method for the scalable synthesis of hydrophilic copper-triazole metal-organic frameworks (Cu-trz) is demonstrated. Numerous open metal sites within the highly crystalline porous structure of Cu-trz are generated through mild thermal activation, enabling its application in liquid-phase ethanol dehydration under ambient conditions. The frameworks with distinct crystallinity and particle sizes were achieved by modifying the synthesis process. The high crystallinity of the framework plays an exclusive role in enhancing water adsorption capacity. With selective water adsorption comparable to commercial zeolite 3 A, Cu-trz MOF emerges as a promising candidate for cost-effective water-ethanol separation.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Chemistry - A European Journal 化学-化学综合

CiteScore

7.90

自引率

4.70%

发文量

1808

审稿时长

1.8 months

期刊介绍： Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.