Importance of Monitoring Frequency for Representation of Dissolved Organic Matter Dynamics in Urban Rivers

IF 4.6 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES
Hongzheng Zhu, Kieran Khamis, David M. Hannah, Stefan Krause
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引用次数: 0

Abstract

In-situ dissolved organic matter (DOM) monitoring frequencies have often been chosen for convenience or based on perceived wisdom, without fully assessing their impact on representation of DOM dynamics. To address this gap, we collected 5-min fluorescence data in an urban headwater and resampled it at coarser intervals to investigate the impact of monitoring frequencies on the detectability of DOM dynamics during storms. Expecting hydrometeorological conditions to modify the impact of monitoring frequency, we categorized 85 storm events into groups: Group A (low intensity, short duration), Group B (high intensity, short duration), and Group C (low intensity, long duration). Surprisingly, our analysis indicated that monitoring frequency has minimal influence on commonly used biogeochemical indexes (e.g., maximum, hysteresis and flushing index), which are employed to characterize solute behavior, regardless of storm type. To facilitate a direct comparison between monitoring frequencies, we back-interpolated coarser data into 5-min intervals and calculated mean squared errors by comparing them with original high-resolution data. Our findings indicated that in colder periods with predominately Type A and C storms, a coarser monitoring frequency (>30 min) can capture DOM dynamics. Conversely, in warmer periods when Type B storms dominate, a finer frequency (≤15 min) is necessary to capture key solute chemograph processes (e.g., first flush and dilution). Generally, we suggest a 15-min monitoring frequency as optimal for similar urban headwater systems, and advocate an adaptive approach based on seasonal variations to improve efficiency, especially when power, data transfer, and storage are constraints.
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来源期刊
Water Resources Research
Water Resources Research 环境科学-湖沼学
CiteScore
8.80
自引率
13.00%
发文量
599
审稿时长
3.5 months
期刊介绍: Water Resources Research (WRR) is an interdisciplinary journal that focuses on hydrology and water resources. It publishes original research in the natural and social sciences of water. It emphasizes the role of water in the Earth system, including physical, chemical, biological, and ecological processes in water resources research and management, including social, policy, and public health implications. It encompasses observational, experimental, theoretical, analytical, numerical, and data-driven approaches that advance the science of water and its management. Submissions are evaluated for their novelty, accuracy, significance, and broader implications of the findings.
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