Comprehensive understanding of the Na1+xZr2SixP3−xO12 solid-state electrolyte in advanced sodium metal batteries: a critical review

IF 32.4 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Xin Wang, Yameng Fan, Jiayang Li, Xinghan Li, Weijie Li, Jiazhao Wang and Wei Kong Pang
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引用次数: 0

Abstract

All solid-state sodium metal batteries (ASSSMBs) have emerged as promising candidates to be a key technology in large-scale energy storage systems relative to mature Li/Na-ion batteries using flammable liquid electrolytes, owing to their abundant sodium resources, robust safety performance, desirable energy density, and favorable reliability and stability. A series of solid-state electrolytes (SSEs), regarded as an essential component of ASSSMBs, have been extensively developed in recent years. Among them, the Na superionic conductor (NASICON)-structure Na1+xZr2SixP3−xO12 (0 ≤ x ≤ 3, defined as NZSP) materials have attracted overwhelming attention as the most appropriate SSEs for the next-generation high energy density ASSSMBs. Herein, this review seeks to provide a comprehensive and in-depth understanding of NZSP SSEs, by first investigating their fundamentals, including composition, crystal structure, Na+-ion conduction mechanism, synthetic methods, and the key challenges associated with the NZSP-based ASSSMBs. Subsequently, comprehensive constructive modification strategies are proposed to optimize integrated NZSP SSE-based ASSSMBs. Finally, informed and strategic perspectives from various angles are summarized, providing potential guidance and possible avenues for further research aimed at achieving exceptional NZSP SSE-based ASSSMBs for practical applications.

Abstract Image

Na1+xZr2SixP3-xO12固态电解质在先进钠金属电池中的应用综述
全固态钠金属电池(ASSSMBs)由于其丰富的钠资源、强大的安全性能、理想的能量密度、良好的可靠性和稳定性,相对于使用可燃液体电解质的成熟锂/钠离子电池,有望成为大规模储能系统的关键技术。一系列固态电解质作为asssmb的重要组成部分,近年来得到了广泛的发展。其中,Na超离子导体(NASICON)-结构Na1+xZr2SixP3-xO12(0≤x≤3,定义为NZSP)材料作为下一代高能量密度ASSSMBs最合适的sss备受关注。在此,本文旨在从研究其基本原理开始,包括组成、晶体结构、Na+离子传导机制、合成方法以及与基于NZSP的asssmb相关的关键挑战,对NZSP asssmb进行全面深入的了解。在此基础上,提出了综合建设性改造策略,对基于NZSP sses的集成asssmb进行优化。最后,总结了不同角度的信息和战略观点,为进一步研究提供了潜在的指导和可能的途径,旨在实现基于NZSP sss的特殊asssmb的实际应用。
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来源期刊
Energy & Environmental Science
Energy & Environmental Science 化学-工程:化工
CiteScore
50.50
自引率
2.20%
发文量
349
审稿时长
2.2 months
期刊介绍: Energy & Environmental Science, a peer-reviewed scientific journal, publishes original research and review articles covering interdisciplinary topics in the (bio)chemical and (bio)physical sciences, as well as chemical engineering disciplines. Published monthly by the Royal Society of Chemistry (RSC), a not-for-profit publisher, Energy & Environmental Science is recognized as a leading journal. It boasts an impressive impact factor of 8.500 as of 2009, ranking 8th among 140 journals in the category "Chemistry, Multidisciplinary," second among 71 journals in "Energy & Fuels," second among 128 journals in "Engineering, Chemical," and first among 181 scientific journals in "Environmental Sciences." Energy & Environmental Science publishes various types of articles, including Research Papers (original scientific work), Review Articles, Perspectives, and Minireviews (feature review-type articles of broad interest), Communications (original scientific work of an urgent nature), Opinions (personal, often speculative viewpoints or hypotheses on current topics), and Analysis Articles (in-depth examination of energy-related issues).
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