One-dimensional C60 arrays in noncovalent benzidine networks

IF 10.5 2区材料科学 Q1 CHEMISTRY, PHYSICAL

Carbon Pub Date : 2024-11-21 DOI:10.1016/j.carbon.2024.119838

Takatsugu Wakahara , Chika Hirata , Dorra Mahdaoui , Kazuko Fujii , Yoshitaka Matsushita , Osamu Ito , Makito Takagi , Tomomi Shimazaki , Masanori Tachikawa , Shinjiro Yagyu , Yubin Liu , Yoshiyuki Nakajima , Takuro Nagai , Kazuhito Tsukagoshi

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引用次数: 0

Abstract

Face-centered cubic packing is typically observed for pristine C₆₀ in the solid state, and one-dimensional alignment structures of pristine C₆₀ in the solid state are extremely rare. This study presents the synthesis of novel one-dimensional aligned C₆₀ in single-cocrystal nanosheets, formed from C₆₀ and N,N,N′,N′-tetraphenylbenzidine (TPB). In C₆₀/TPB, which exhibits ambipolar charge transport characteristics, TPB serves as a molecular receptor to facilitate the formation of noncovalent networks wherein C₆₀ organizes into one-dimensional arrays. The resulting C₆₀/TPB nanosheets give rise to a distinct absorption band in the near-infrared region, suggesting the occurrence of charge-transfer interactions between the C₆₀ and TPB frameworks within the cocrystals.

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来源期刊

Carbon 工程技术-材料科学：综合

CiteScore

20.80

自引率

7.30%

发文量

审稿时长

23 days

期刊介绍： The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.