Hyunji Son, Dong Hyun Choi, Kyungho Park, Jusung Chung, Byung Ha Kang, Hyun Jae Kim
{"title":"Pseudologic Optical Circuit Method for Advanced Color Sensing in IGZO Phototransistor Arrays with Chlorophyll Absorption Layers","authors":"Hyunji Son, Dong Hyun Choi, Kyungho Park, Jusung Chung, Byung Ha Kang, Hyun Jae Kim","doi":"10.1021/acsami.4c12979","DOIUrl":null,"url":null,"abstract":"Recently, the elimination of color filters has become a key focus in photodetector research because of the potential to create more compact and cost-effective sensor systems. In this study, a novel concept of a filter-free color-discrimination photosensor using an indium gallium zinc oxide (IGZO, In/Ga/Zn = 3.1:2.6:1.0)-based phototransistor with an integrated chlorophyll absorption layer (CAL) and a solution-processed oxide absorption layer (SAL) was developed. Chlorophyll, known for its role in photosynthesis as a natural light absorber, offers distinct characteristics compared to conventional photodetectors (i.e., SAL/IGZO), whereby the photoresponsivity decreases with increasing wavelength. Using the ability of chlorophyll to absorb blue and red light, the proposed CAL/IGZO phototransistor exhibited a higher photoresponsivity to red light than to green light. The device achieved a photoresponsivity of 1570 A/W for red light and 681 A/W for green light, with a photosensitivity of 8.35 × 10<sup>5</sup> and 8.96 × 10<sup>4</sup> and a detectivity of 8.47 × 10<sup>11</sup> and 6.80 × 10<sup>10</sup> Jones, respectively, under an illumination intensity of 1 mW/mm<sup>2</sup>. Furthermore, by integrating the proposed CAL/IGZO phototransistor with a SAL/IGZO phototransistor, which exhibited a different order of photoresponse across RGB wavelengths, an innovative color-discrimination pixel pseudologic circuit was successfully developed. The capability of this circuit to distinguish colors across various light intensities was validated through experimental data and SPICE simulations, with the output voltage ranges confirmed as −2.61 to −3.51 V for red, 1.56 to 2.69 V for green, and −0.22 to −0.68 V for blue over light intensities from 0.1 to 3 mW/mm<sup>2</sup>. This innovative approach allows effective color detection without conventional color filters, providing an advanced solution for photodetection technologies.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"261 1","pages":""},"PeriodicalIF":8.3000,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Materials & Interfaces","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsami.4c12979","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Recently, the elimination of color filters has become a key focus in photodetector research because of the potential to create more compact and cost-effective sensor systems. In this study, a novel concept of a filter-free color-discrimination photosensor using an indium gallium zinc oxide (IGZO, In/Ga/Zn = 3.1:2.6:1.0)-based phototransistor with an integrated chlorophyll absorption layer (CAL) and a solution-processed oxide absorption layer (SAL) was developed. Chlorophyll, known for its role in photosynthesis as a natural light absorber, offers distinct characteristics compared to conventional photodetectors (i.e., SAL/IGZO), whereby the photoresponsivity decreases with increasing wavelength. Using the ability of chlorophyll to absorb blue and red light, the proposed CAL/IGZO phototransistor exhibited a higher photoresponsivity to red light than to green light. The device achieved a photoresponsivity of 1570 A/W for red light and 681 A/W for green light, with a photosensitivity of 8.35 × 105 and 8.96 × 104 and a detectivity of 8.47 × 1011 and 6.80 × 1010 Jones, respectively, under an illumination intensity of 1 mW/mm2. Furthermore, by integrating the proposed CAL/IGZO phototransistor with a SAL/IGZO phototransistor, which exhibited a different order of photoresponse across RGB wavelengths, an innovative color-discrimination pixel pseudologic circuit was successfully developed. The capability of this circuit to distinguish colors across various light intensities was validated through experimental data and SPICE simulations, with the output voltage ranges confirmed as −2.61 to −3.51 V for red, 1.56 to 2.69 V for green, and −0.22 to −0.68 V for blue over light intensities from 0.1 to 3 mW/mm2. This innovative approach allows effective color detection without conventional color filters, providing an advanced solution for photodetection technologies.
期刊介绍:
ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.