Functionalization of covalent organic frameworks via multicomponent reactions

IF 10.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Xue-Hui Liu, Peng-Lai Wang, Wei Wang, San-Yuan Ding
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引用次数: 0

Abstract

Functionalized covalent organic frameworks (COFs) represent a fascinating class of porous materials that have attracted widespread interest due to their modifiable structures and impressive potential applications. However, the construction of functionalized COFs remains difficult as it requires simultaneous consideration of robust linkages, diversified structures, and tailorable functionalities. Recently, the introduction of multicomponent reactions (MCRs) into COF synthesis opens new avenues for creating highly stable and function-oriented COF materials, marking a significant advance in the development of COFs. This minireview summarizes the types of MCRs used in COF synthesis, highlights the functionalization strategies of COFs via MCRs, and provides insights on the key challenges and future frontiers in this field.

通过多组分反应的共价有机框架的功能化
功能化共价有机框架(COFs)是一类极具吸引力的多孔材料,由于其可修饰的结构和令人印象深刻的潜在应用而引起了广泛的兴趣。然而,功能化COFs的构建仍然很困难,因为它需要同时考虑强大的联系、多样化的结构和可定制的功能。近年来,将多组分反应(mcr)引入到COF合成中,为制备高稳定性和功能导向的COF材料开辟了新的途径,标志着COF的发展取得了重大进展。本文综述了用于COF合成的mcr的类型,重点介绍了通过mcr实现COF功能化的策略,并对该领域的关键挑战和未来前沿提出了见解。
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来源期刊
Science China Chemistry
Science China Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
14.40
自引率
7.30%
发文量
3787
审稿时长
2.2 months
期刊介绍: Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field. Categories of articles include: Highlights. Brief summaries and scholarly comments on recent research achievements in any field of chemistry. Perspectives. Concise reports on thelatest chemistry trends of interest to scientists worldwide, including discussions of research breakthroughs and interpretations of important science and funding policies. Reviews. In-depth summaries of representative results and achievements of the past 5–10 years in selected topics based on or closely related to the research expertise of the authors, providing a thorough assessment of the significance, current status, and future research directions of the field.
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