{"title":"Functionalization of covalent organic frameworks via multicomponent reactions","authors":"Xue-Hui Liu, Peng-Lai Wang, Wei Wang, San-Yuan Ding","doi":"10.1007/s11426-024-2213-2","DOIUrl":null,"url":null,"abstract":"<div><p>Functionalized covalent organic frameworks (COFs) represent a fascinating class of porous materials that have attracted widespread interest due to their modifiable structures and impressive potential applications. However, the construction of functionalized COFs remains difficult as it requires simultaneous consideration of robust linkages, diversified structures, and tailorable functionalities. Recently, the introduction of multicomponent reactions (MCRs) into COF synthesis opens new avenues for creating highly stable and function-oriented COF materials, marking a significant advance in the development of COFs. This minireview summarizes the types of MCRs used in COF synthesis, highlights the functionalization strategies of COFs via MCRs, and provides insights on the key challenges and future frontiers in this field.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":772,"journal":{"name":"Science China Chemistry","volume":"67 12","pages":"3906 - 3914"},"PeriodicalIF":10.4000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Chemistry","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1007/s11426-024-2213-2","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Functionalized covalent organic frameworks (COFs) represent a fascinating class of porous materials that have attracted widespread interest due to their modifiable structures and impressive potential applications. However, the construction of functionalized COFs remains difficult as it requires simultaneous consideration of robust linkages, diversified structures, and tailorable functionalities. Recently, the introduction of multicomponent reactions (MCRs) into COF synthesis opens new avenues for creating highly stable and function-oriented COF materials, marking a significant advance in the development of COFs. This minireview summarizes the types of MCRs used in COF synthesis, highlights the functionalization strategies of COFs via MCRs, and provides insights on the key challenges and future frontiers in this field.
期刊介绍:
Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field.
Categories of articles include:
Highlights. Brief summaries and scholarly comments on recent research achievements in any field of chemistry.
Perspectives. Concise reports on thelatest chemistry trends of interest to scientists worldwide, including discussions of research breakthroughs and interpretations of important science and funding policies.
Reviews. In-depth summaries of representative results and achievements of the past 5–10 years in selected topics based on or closely related to the research expertise of the authors, providing a thorough assessment of the significance, current status, and future research directions of the field.