Shape-stabilized, thermally conductive phase-change composites for thermal energy storage

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL
Guanyue Zeng, Yihang Li, Yuzhu Xiong
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引用次数: 0

Abstract

Phase-change materials (PCMs) with three-dimensional thermally conductive skeletons show promise for thermal energy storage, but they have poor stability. Therefore, based on hydrogen bonding between graphene oxide and polyvinyl alcohol, a shape-stable thermally conductive graphene oxide/graphene nanoplates/polyvinyl alcohol (GO/GNP/PVAs) 3D porous skeleton was prepared by a simple vacuum freeze–drying method in this paper. To further improve the thermal conductivity of the GO/GNP/PVAs 3D porous skeleton, so carbonization is applied on it. After encapsulating polyethylene glycol (PEG) in the skeleton, a thermally conductive phase-change composite with good shape stability was obtained, even at a PEG loading as high as 96.1%. The carbonized C-GO/GNP/PVAs/PEG phase-change composites exhibited higher thermal conductivity (1.57 W m−1 K−1) than uncarbonized GO/GNP/PVAs/PEG phase-change composites (0.52 W m−1 K−1). This was mainly due to the low thermal conductivity GO annealing into high thermal conductivity reduced graphene oxide (rGO), which formed a conductive three-dimensional network. Meanwhile, the formation of a carbon skeleton by PVA chains after annealing also improved the thermal conductivity of the composites. The C-GO/GNP/PVAs/PEG phase-change composites also showed excellent solar-to-heat conversion properties.

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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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