A critical assessment of ionic liquid-based aqueous biphasic systems for biomolecules extraction and CO2 absorption

IF 5.5 Q1 ENGINEERING, CHEMICAL

Chemical Engineering Journal Advances Pub Date : 2024-10-28 DOI:10.1016/j.ceja.2024.100670

Viggy Wee Gee Tan , Yazan Abuhasheesh , Doris Ying Ying Tang , Yongyu Zhang , Zengling Ma , Lin Chen , Rambabu Krishnamoorthy , Pau Loke Show

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引用次数: 0

Abstract

Ionic liquids (ILs) are green designer solvents that have gained research interest in industrial applications, including solvent chemistry, catalysis, and electrochemistry. Recent advances in ionic liquid-based aqueous biphasic systems (IL-ABSs) have broadened their biological applications. This review discusses the state-of-the-art of its biotechnological application in biomolecules recovery and phase separation mechanism. The prospects of ILs as green solvents and their toxicity and applicability in carbon dioxide (CO₂) capture are discussed. The correlation between the structures and toxicity of ILs is also provided, with a special emphasis on the synthesis of safer ILs. This review examines the significance and techniques in recovering and reusing phase-forming agents such as ILs. The incorporation of machine learning (ML) algorithms to predict the toxicity and CO₂ capture properties, as well as the scaling up of IL-ABSs, is also explored.

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离子液体为基础的水双相系统的生物分子提取和二氧化碳吸收的关键评估

离子液体是一种绿色设计溶剂，在溶剂化学、催化和电化学等工业领域得到了广泛的应用。近年来离子液体基双水相体系（IL-ABSs）的研究进展拓宽了其生物应用领域。本文综述了其在生物分子回收和相分离机理方面的生物技术应用进展。讨论了有机溶剂作为绿色溶剂的前景及其在二氧化碳捕集中的毒性和适用性。本文还介绍了化合物的结构与毒性之间的关系，并着重介绍了更安全的化合物的合成方法。本文综述了合成相剂（il）回收和再利用的意义和技术。还探讨了结合机器学习（ML）算法来预测毒性和二氧化碳捕获特性，以及il - abs的放大。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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