Yonghua Zhong, Zi-Ming Ye, Fanrui Sha, Haomiao Xie, Xiaoliang Wang, Chenghui Zhang, Daofei Lv*, Yongwei Chen*, Zhibo Li and Omar K. Farha*,
{"title":"Reduced-Symmetry Ligand Constructed Y-Based Metal–Organic Framework for Inverse Propane/Propylene Separation","authors":"Yonghua Zhong, Zi-Ming Ye, Fanrui Sha, Haomiao Xie, Xiaoliang Wang, Chenghui Zhang, Daofei Lv*, Yongwei Chen*, Zhibo Li and Omar K. Farha*, ","doi":"10.1021/acsmaterialslett.4c0195710.1021/acsmaterialslett.4c01957","DOIUrl":null,"url":null,"abstract":"<p >The rational design of organic ligands is crucial in the development of new metal–organic frameworks (MOFs) to enrich the structural diversity and application potential of MOFs. For example, tuning the ligand symmetry has been widely utilized in the construction of new MOFs with specific properties. Herein, a novel Y-based MOF (denoted as NU-60) was generated by selecting a tritopic carboxylate ligand with reduced symmetry. Compared with its tritopic counterpart with relatively high symmetry, NU-60 has a new (3,12)-connected topology, highlighting the power of the ligand desymmetrization method to enrich MOF structural diversity. Gas adsorption studies demonstrated that NU-60 is a propane-selective adsorbent for efficient propane/propylene separation.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"6 12","pages":"5348–5353 5348–5353"},"PeriodicalIF":9.6000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Materials Letters","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsmaterialslett.4c01957","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The rational design of organic ligands is crucial in the development of new metal–organic frameworks (MOFs) to enrich the structural diversity and application potential of MOFs. For example, tuning the ligand symmetry has been widely utilized in the construction of new MOFs with specific properties. Herein, a novel Y-based MOF (denoted as NU-60) was generated by selecting a tritopic carboxylate ligand with reduced symmetry. Compared with its tritopic counterpart with relatively high symmetry, NU-60 has a new (3,12)-connected topology, highlighting the power of the ligand desymmetrization method to enrich MOF structural diversity. Gas adsorption studies demonstrated that NU-60 is a propane-selective adsorbent for efficient propane/propylene separation.
期刊介绍：
ACS Materials Letters is a journal that publishes high-quality and urgent papers at the forefront of fundamental and applied research in the field of materials science. It aims to bridge the gap between materials and other disciplines such as chemistry, engineering, and biology. The journal encourages multidisciplinary and innovative research that addresses global challenges. Papers submitted to ACS Materials Letters should clearly demonstrate the need for rapid disclosure of key results. The journal is interested in various areas including the design, synthesis, characterization, and evaluation of emerging materials, understanding the relationships between structure, property, and performance, as well as developing materials for applications in energy, environment, biomedical, electronics, and catalysis. The journal has a 2-year impact factor of 11.4 and is dedicated to publishing transformative materials research with fast processing times. The editors and staff of ACS Materials Letters actively participate in major scientific conferences and engage closely with readers and authors. The journal also maintains an active presence on social media to provide authors with greater visibility.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
