A Broadband Light-Trapping Nanostructure for InGaP/GaAs Dual-Junction Solar Cells Using Nanosphere Lithography-Assisted Chemical Etching

IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2024-09-29 DOI:10.1002/solr.202400531
Shang-Hsuan Wu, Gabriel Cossio, Daniel Derkacs, Edward T. Yu
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Abstract

III–V-based multijunction solar cells have become the leading power generation technology for space applications due to their high power conversion efficiency and reliable performance in extraterrestrial environments. Thinning down the absorber layers of multijunction solar cells can considerably reduce the production cost and improve their radiation hardness. Recent advances in ultrathin GaAs single-junction solar cells suggest the development of light-trapping nanostructures to increase light absorption in optically thin layers within III–V-based multijunction solar cells. Herein, a novel and highly scalable nanosphere lithography-assisted chemical etching method to fabricate light-trapping nanostructures in InGaP/GaAs dual-junction solar cells is studied. Numerical models show that integrating the nanostructured Al2O3/Ag rear mirror significantly enhances the broadband absorption within the GaAs bottom cell. Results demonstrate that the light-trapping nanostructures effectively increase the short-circuit current density in GaAs bottom cells from 14.04 to 15.06 mA cm−2. The simulated nanostructured InGaP/GaAs dual-junction structure shows improved current matching between the GaAs bottom cell and the InGaP top cell, resulting in 1.12x higher power conversion efficiency. These findings highlight the potential of light-trapping nanostructures to improve the performance of III-V-based multijunction photovoltaic systems, particularly for high-efficiency applications in space.

Abstract Image

利用纳米球光刻辅助化学蚀刻技术制备InGaP/GaAs双结太阳能电池的宽带光捕获纳米结构
iii - v型多结太阳能电池由于其高功率转换效率和可靠的地外环境性能,已成为空间应用的主要发电技术。薄化多结太阳能电池的吸收层可以大大降低生产成本,提高其辐射硬度。超薄砷化镓单结太阳能电池的最新进展表明,在iii - v基多结太阳能电池中,光捕获纳米结构的发展可以增加光学薄层的光吸收。本文研究了一种新型的、高度可扩展的纳米球光刻辅助化学蚀刻方法,用于在InGaP/GaAs双结太阳能电池中制备光捕获纳米结构。数值模型表明,集成纳米结构的Al2O3/Ag后视镜显著增强了GaAs底电池内的宽带吸收。结果表明,捕光纳米结构有效地提高了砷化镓底部电池的短路电流密度,从14.04 mA cm−2提高到15.06 mA cm−2。模拟的纳米结构InGaP/GaAs双结结构表明,GaAs底部电池和InGaP顶部电池之间的电流匹配得到改善,功率转换效率提高了1.12倍。这些发现强调了光捕获纳米结构在改善iii - v型多结光伏系统性能方面的潜力,特别是在太空中的高效应用。
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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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