Research and optimization of slit issues in the kW-scale redox flow batteries stack

IF 8.9 2区 工程技术 Q1 ENERGY & FUELS
Yingchun Niu, Shengwei Yuan, Ziyu Liu, Ali Heydari, Yinping Liu, Wei Qiu, Chunming Xu, Quan Xu
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Abstract

The assembly of the frame and bipolar plates in redox flow batteries (RFBs) often results in assembly gaps, forming ‘slit.’ Due to differing coefficients of thermal expansion between the plate frame and bipolar plates, thermal expansion and contraction occur under the influence of assembly environment temperatures and operational temperatures of RFBs, exacerbating the ‘slit’ issue. The presence of ‘slits’ can reduce the utilization rate of the electrolyte and decrease mass transfer efficiency during the battery cycling process. However, the flow channel design for kilowatt (kW)-scale stacks often overlooks the impact of these slits. Therefore, this paper examines the influence of ‘slit’ structures on the flow characteristics of electrolytes within carbon cloth using kW-scale stacks with interdigitated flow channel structures as an example, and optimizes the interdigitated flow field with slits. The study analyzes the flow characteristics of electrolytes on carbon cloth in flow field structures with no slits, slits at both ends and slits on three sides. It further investigates the effects of slit width and the length of interdigitated flow channels on the flow patterns of electrolytes on carbon cloth when slits are present. Through numerical simulation, velocity and pressure distribution maps at the center of the carbon cloth, as well as velocity distributions at various positions, are obtained. The results show that slits affect the position and extent of the low-speed zone on the carbon cloth. As slit width increases, the resistance of the slit decreases, gradually increasing the flow velocity of the electrolyte towards the carbon cloth. However, when the slit width exceeds 0.5 mm, the impact of the slit on flow over the carbon cloth remains largely unchanged. With a fixed slit width of 0.5 mm, increasing the length of the interdigitated flow channels reduces the flow velocity and pressure within the carbon cloth but significantly improves the uniformity of the carbon cloth. Extending the interdigitated flow channel length by 15 mm demonstrates the best overall effect.
kw级氧化还原液流电池堆缝问题的研究与优化
在氧化还原液流电池(rfb)中,框架和双极板的组装通常会产生组装间隙,形成“狭缝”。由于板框和双极板之间的热膨胀系数不同,在rfb的装配环境温度和工作温度的影响下会发生热膨胀和收缩,从而加剧了“狭缝”问题。在电池循环过程中,“缝隙”的存在会降低电解液的利用率,降低传质效率。然而,千瓦级堆的流道设计往往忽略了这些狭缝的影响。因此,本文以具有交错流道结构的kw级堆为例,研究了“狭缝”结构对碳布内电解质流动特性的影响,并对具有狭缝的交错流场进行了优化。研究了无缝、两端有缝和三面有缝三种流场结构下电解液在碳布上的流动特性。进一步研究了当有狭缝存在时,狭缝宽度和交错流道长度对电解液在碳布上的流动规律的影响。通过数值模拟,得到了炭布中心的速度和压力分布图,以及各位置的速度分布图。结果表明,狭缝对碳布上低速区的位置和范围有影响。随着狭缝宽度的增大,狭缝的阻力减小,电解液流向碳布的流速逐渐增大。然而,当狭缝宽度超过0.5 mm时,狭缝对碳布流动的影响基本保持不变。当狭缝宽度固定为0.5 mm时,增加交错流道的长度会降低碳布内部的流速和压力,但会显著改善碳布的均匀性。将交叉流道长度延长15mm,整体效果最佳。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of energy storage
Journal of energy storage Energy-Renewable Energy, Sustainability and the Environment
CiteScore
11.80
自引率
24.50%
发文量
2262
审稿时长
69 days
期刊介绍: Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.
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