Investigation of two sandwich-structured nanohybrid coating derived from graphene oxide/carbon nanotube on interfacial adhesion and fracture toughness of carbon fiber composites
Qing Wu , Yating Li , Jun Chang , Dan Jin , Bolin Xiao , Renjie Yao , Jianfeng Zhu
{"title":"Investigation of two sandwich-structured nanohybrid coating derived from graphene oxide/carbon nanotube on interfacial adhesion and fracture toughness of carbon fiber composites","authors":"Qing Wu , Yating Li , Jun Chang , Dan Jin , Bolin Xiao , Renjie Yao , Jianfeng Zhu","doi":"10.1016/j.compositesb.2024.112007","DOIUrl":null,"url":null,"abstract":"<div><div>Designing stronger interphase towards solving the long-standing dilemma of interfacial delamination is critical for stable application of carbon fiber composites. Herein, nano-scale sandwich-structured coatings, where carbon nanotubes (CNTs) were uniformly anchored on both sides of graphene oxide (GO) layer (abbreviated as C/GO/C) and its reverse, that is double GO layers encapsulated CNT network (G/CNT/G in short), were reported around fiber periphery via vacuum filtration method. The effects of surface structure differences on interfacial shear strength (IFSS) and fracture toughness were compared in epoxy matrix. Impressively, composite incorporating G/CNT/G modified fiber delivered prominent IFSS and interfacial fracture toughness of 114.6 MPa and 137.0 J/m<sup>2</sup>, 105.7 % and 279.5 % increases over control fiber composite. This strategy was also superior to C/GO/C and other reported GO and CNT related works. The main factors for maximal IFSS offered by G/CNT/G are that two GO panels enrich active sites to tightly bridge fiber and epoxy, as well as its layered feature and large surface area provide a stable “skeleton” at interphase for stress transfer. Additionally, the G/CNT/G “skeleton” is closer to sandwich structure of iris leaf, in which the porous CNT intermediate network creates larger deformation and adsorb more energy, leading to peak interfacial fracture toughness.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"291 ","pages":"Article 112007"},"PeriodicalIF":12.7000,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Part B: Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359836824008205","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Designing stronger interphase towards solving the long-standing dilemma of interfacial delamination is critical for stable application of carbon fiber composites. Herein, nano-scale sandwich-structured coatings, where carbon nanotubes (CNTs) were uniformly anchored on both sides of graphene oxide (GO) layer (abbreviated as C/GO/C) and its reverse, that is double GO layers encapsulated CNT network (G/CNT/G in short), were reported around fiber periphery via vacuum filtration method. The effects of surface structure differences on interfacial shear strength (IFSS) and fracture toughness were compared in epoxy matrix. Impressively, composite incorporating G/CNT/G modified fiber delivered prominent IFSS and interfacial fracture toughness of 114.6 MPa and 137.0 J/m2, 105.7 % and 279.5 % increases over control fiber composite. This strategy was also superior to C/GO/C and other reported GO and CNT related works. The main factors for maximal IFSS offered by G/CNT/G are that two GO panels enrich active sites to tightly bridge fiber and epoxy, as well as its layered feature and large surface area provide a stable “skeleton” at interphase for stress transfer. Additionally, the G/CNT/G “skeleton” is closer to sandwich structure of iris leaf, in which the porous CNT intermediate network creates larger deformation and adsorb more energy, leading to peak interfacial fracture toughness.
期刊介绍:
Composites Part B: Engineering is a journal that publishes impactful research of high quality on composite materials. This research is supported by fundamental mechanics and materials science and engineering approaches. The targeted research can cover a wide range of length scales, ranging from nano to micro and meso, and even to the full product and structure level. The journal specifically focuses on engineering applications that involve high performance composites. These applications can range from low volume and high cost to high volume and low cost composite development.
The main goal of the journal is to provide a platform for the prompt publication of original and high quality research. The emphasis is on design, development, modeling, validation, and manufacturing of engineering details and concepts. The journal welcomes both basic research papers and proposals for review articles. Authors are encouraged to address challenges across various application areas. These areas include, but are not limited to, aerospace, automotive, and other surface transportation. The journal also covers energy-related applications, with a focus on renewable energy. Other application areas include infrastructure, off-shore and maritime projects, health care technology, and recreational products.