Optimizing calcination temperature to improve the compressive strength of coal gasification slag-based alkali-activated materials by reducing carbon content and adjusting polymerization degree

IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY
Xiaowei Gu , Zhihang Hu , Ziyang Hu , Jianping Liu , Qing Wang , Moncef L. Nehdif
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引用次数: 0

Abstract

The efficient utilization of coal gasification slag (CGS) to prepare alkali-activated materials (AAMs) presents a significant opportunity for addressing the challenges associated with solid waste accumulation and environmental degradation. However, the aluminosilicate glass in CGS is highly polymerized, rendering it challenging to stimulate its potential reactivity. Additionally, the presence of residual carbon impedes the hydration process in AAMs, thereby limiting its applicability. This study focuses on the residual carbon content and polymerization degree of CGS after calcination treatment to overcome these challenges and improve the reactivity of CGS. Results revealed that residual carbon in CGS underwent thermal decomposition, increasing the proportion of aluminosilicate glass components. The degree of polymerization of CGS was reduced by 25 % under calcined conditions at 550°C, whereas at 700°C, CGS recrystallized, and the aluminosilicates were again highly polymerized. The highest reactivity of CGS was observed after calcination at 550°C. The 28 days compressive strength of the prepared AAM paste reached 47.5 MPa, representing an increase of 18.45 % compared to the control. This study innovatively elucidates the physicochemical properties of calcined CGS. It highlights the critical importance of controlling calcination conditions to manage the polymerization degree and phase transformations during carbon removal, thereby enhancing the reactivity and performance of AAMs.
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来源期刊
Construction and Building Materials
Construction and Building Materials 工程技术-材料科学:综合
CiteScore
13.80
自引率
21.60%
发文量
3632
审稿时长
82 days
期刊介绍: Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged. Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.
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