Nghia P. Tran , Marc-Antoine Sani , Tuan N. Nguyen , Tuan D. Ngo
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引用次数: 0
Abstract
This study investigates the effect of electrolytic copper powder (ECP) and graphene oxide (GO) on geopolymerisation and microstructural characterisation of one-part alkali-activated material (AAM), which strongly correlates to its thermal-mechanical performance. Various analytical techniques were employed to evaluate the chemical modifications, reaction kinetics, microstructure and pore structure induced by these additives, including X-ray diffraction (XRD), fourier transform infrared (FTIR), isothermal calorimetry, scanning electron microscopy coupling with energy dispersive spectroscopy (SEM/EDS), nitrogen adsorption-desorption (NAD) and nuclear magnetic resonance (NMR). The result findings show that the dissolved Cu2+ ions affect Al–O linkages at AlIV sites in the geopolymer framework. The presence of ECP and GO also reduce the physically-bound water within intralayer and promote the development of highly-crosslinked gel networks characterised by Q4(3Al) sites. ECP in forms of dissolved ions exhibits the adsorption mechanism onto C-(N)-A-S-H gels, while the remaining ECP particles with coral-like shape serve as micro-aggregate filling in the pores. The incorporation of ECP and GO accelerates the geopolymerisation with further gel formation and densification (reduced both total porosity and pore size). Both forms of ECP significantly enhance the thermal conductivity of the geopolymer, and this effect is further amplified by GO inclusion due to higher densification. Overall, the effect of ECP and GO significantly enhances the thermal and mechanical properties of one-part AAM, making them a promising approach for advanced materials such as thermal energy storage (TES) materials.
期刊介绍:
Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged.
Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.