Effect of self-assembly of nucleator adsorbed at the interface by H-bonding on the crystallization and mechanical behaviors of iPP hybrids

IF 4.1 2区 化学 Q2 POLYMER SCIENCE
Wen-yue Zhuo, Jian Wang, Yan-hua Niu, Ya-dong Lv
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引用次数: 0

Abstract

DCHT (N, N-dicyclohexylterephthalamide) as a common type of β-nucleator could self-assemble into various morphologies in iPP (isotactic polypropylene) matrix and further affect its crystallization behaviors. In this study, a third component of PA11 (polyamide 11) was intentionally introduced into iPP hybrids to tune the adsorption and assembly of DCHT by forming hydrogen bonds, whose effects on the crystallization and mechanical properties of iPP hybrids at different processing temperature (Tf) were investigated in detail. It is observed that DCHT could form flower-like crystals at higher Tf, while it tends to aggregate and form rod-like crystal with high concentration in the hybrids. DSC results show that DCHT could lost its nucleation ability at low concentration. With the increase of DCHT concentration, the residual DCHT in the matrix could induce the crystallization of iPP as β-nucleation site. A core-shell structure was observed for the first time in which the shell as the interface layer is formed by DCHT assembly and iPP crystal. It is a key to greatly improve the toughness of the hybrids and the strength of the interface layer between PA11 and iPP by self-assembling and crystallizing at the interface. By changing the PA11 hard core to the TPU (Thermoplastic polyurethanes) soft core at a higher Tf of 280 °C, the impact strength of iPP/20TPU/0.5DCHT hybrid reaches 13 kJ/m2, which is 4 times of pure iPP, while the tensile strength only slightly decreases. This study provided a new strategy to optimize the mechanical properties of iPP by forming the core-shell structure and meanwhile tunning the assembly of nucleator at the interface.

Abstract Image

Abstract Image

通过 H 键吸附在界面上的成核剂的自组装对 iPP 混合物的结晶和机械行为的影响
DCHT(N,N-二环己基对苯二甲酰胺)作为一种常见的 β 核物,可在 iPP(异构聚丙烯)基体中自组装成各种形态,并进一步影响其结晶行为。本研究有意在 iPP 混合物中引入第三种成分 PA11(聚酰胺 11),通过形成氢键来调节 DCHT 的吸附和组装,并详细研究了其在不同加工温度(Tf)下对 iPP 混合物结晶和机械性能的影响。结果表明,在较高的 Tf 下,DCHT 可形成花状晶体,而在混合物中浓度较高时,DCHT 则倾向于聚集并形成棒状晶体。DSC 结果表明,DCHT 在低浓度时会失去成核能力。随着 DCHT 浓度的增加,基质中残留的 DCHT 可作为 β 成核位点诱导 iPP 结晶。首次观察到由 DCHT 组装和 iPP 晶体形成的以壳为界面层的核壳结构。通过在界面上的自组装和结晶,这是大大提高混合材料韧性以及 PA11 和 iPP 之间界面层强度的关键。在 280 oC 的较高温度下,将 PA11 硬核改为 TPU(热塑性聚氨酯)软核,iPP/20TPU/0.5DCHT 混合物的冲击强度达到 13 kJ/m2,是纯 iPP 的 4 倍,而拉伸强度仅略有下降。这项研究提供了一种新的策略,通过形成核壳结构,同时调节界面上成核剂的组装,优化 iPP 的机械性能。
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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