Fangyi Xu, Shuxin Zhao, Junjie Song, Yu Peng, Baowei Su
{"title":"Organic Solvent Nanofiltration Membrane with In Situ Constructed Covalent Organic Frameworks as Separation Layer.","authors":"Fangyi Xu, Shuxin Zhao, Junjie Song, Yu Peng, Baowei Su","doi":"10.3390/membranes14110234","DOIUrl":null,"url":null,"abstract":"<p><p>Organic solvent nanofiltration (OSN) technology is advantageous for separating mixtures of organic solutions owing to its low energy consumption and environmental friendliness. Covalent organic frameworks (COFs) are good candidates for enhancing the efficiency of solvent transport and ensuring precise molecular sieving of OSN membranes. In this study, p-phenylenediamine (Pa) and 1,3,5-trimethoxybenzene (Tp) are used to construct, in situ, a TpPa COF skin layer via interfacial polymerization (IP) on a polyimide substrate surface. After subsequent crosslinking and activation steps, a kind of TpPa/polyimide (PI) OSN membrane is obtained. Under optimized fabrications, this OSN membrane exhibits an ethanol permeance of 58.0 LMH/MPa, a fast green FCF (FGF) rejection of 96.2%, as well as a pure <i>n</i>-hexane permeance of 102.0 LMH/MPa. Furthermore, the TpPa/PI OSN membrane exhibits good solvent resistance, which makes it suitable for the separation, purification, and concentration of organic solvents.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"14 11","pages":""},"PeriodicalIF":3.3000,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11596232/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Membranes","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.3390/membranes14110234","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Organic solvent nanofiltration (OSN) technology is advantageous for separating mixtures of organic solutions owing to its low energy consumption and environmental friendliness. Covalent organic frameworks (COFs) are good candidates for enhancing the efficiency of solvent transport and ensuring precise molecular sieving of OSN membranes. In this study, p-phenylenediamine (Pa) and 1,3,5-trimethoxybenzene (Tp) are used to construct, in situ, a TpPa COF skin layer via interfacial polymerization (IP) on a polyimide substrate surface. After subsequent crosslinking and activation steps, a kind of TpPa/polyimide (PI) OSN membrane is obtained. Under optimized fabrications, this OSN membrane exhibits an ethanol permeance of 58.0 LMH/MPa, a fast green FCF (FGF) rejection of 96.2%, as well as a pure n-hexane permeance of 102.0 LMH/MPa. Furthermore, the TpPa/PI OSN membrane exhibits good solvent resistance, which makes it suitable for the separation, purification, and concentration of organic solvents.
MembranesChemical Engineering-Filtration and Separation
CiteScore
6.10
自引率
16.70%
发文量
1071
审稿时长
11 weeks
期刊介绍：
Membranes (ISSN 2077-0375) is an international, peer-reviewed open access journal of separation science and technology. It publishes reviews, research articles, communications and technical notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
