Highly permeable acid-resistant polyamine hollow fiber nanofiltration membrane fabricated by secondary interfacial polymerization reactions

IF 8.4 1区工程技术 Q1 ENGINEERING, CHEMICAL

Journal of Membrane Science Pub Date : 2024-11-15 DOI:10.1016/j.memsci.2024.123502

Yurong Yin , Can Li , Daniel Yee Fan Ng , Rong Wang

{"title":"Highly permeable acid-resistant polyamine hollow fiber nanofiltration membrane fabricated by secondary interfacial polymerization reactions","authors":"Yurong Yin , Can Li , Daniel Yee Fan Ng , Rong Wang","doi":"10.1016/j.memsci.2024.123502","DOIUrl":null,"url":null,"abstract":"<div><div>The development of acid-resistant nanofiltration (NF) membranes has drawn much attention due to their application in industrial wastewater treatment. In this work, we utilized polyethyleneimine (PEI) and cyanuric chloride (CC) to conduct the first interfacial polymerization (IP) reaction on the polyethersulfone (PES) hollow fiber substrate, followed by the secondary IP process using tris(2-aminoethyl) amine (TAEA) to react with the residual chloride groups after the first IP to improve the positive charge intensity of the membrane surface. Compared to the pristine membrane formed after the first IP, the TAEA-optimized membrane exhibited a high pure water permeability (PWP) of 25.2 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup> and nearly 90 % rejection to MgCl<sub>2</sub> at 2 bar operating pressure. Meanwhile, when treating synthetic electroplating rinse water, the membrane was still able to achieve 85 % rejections to Cu<sup>2+</sup> and Ni<sup>2+</sup> ions during a 7-day operation test under pH of 1 condition. The results demonstrate the good potential of the membrane for heavy metal ions removal in industrial acidic wastewater.</div></div>","PeriodicalId":368,"journal":{"name":"Journal of Membrane Science","volume":"716 ","pages":"Article 123502"},"PeriodicalIF":8.4000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Membrane Science","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0376738824010962","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}

引用次数: 0

Abstract

The development of acid-resistant nanofiltration (NF) membranes has drawn much attention due to their application in industrial wastewater treatment. In this work, we utilized polyethyleneimine (PEI) and cyanuric chloride (CC) to conduct the first interfacial polymerization (IP) reaction on the polyethersulfone (PES) hollow fiber substrate, followed by the secondary IP process using tris(2-aminoethyl) amine (TAEA) to react with the residual chloride groups after the first IP to improve the positive charge intensity of the membrane surface. Compared to the pristine membrane formed after the first IP, the TAEA-optimized membrane exhibited a high pure water permeability (PWP) of 25.2 L m⁻² h⁻¹ bar⁻¹ and nearly 90 % rejection to MgCl₂ at 2 bar operating pressure. Meanwhile, when treating synthetic electroplating rinse water, the membrane was still able to achieve 85 % rejections to Cu²⁺ and Ni²⁺ ions during a 7-day operation test under pH of 1 condition. The results demonstrate the good potential of the membrane for heavy metal ions removal in industrial acidic wastewater.

Abstract Image

查看原文本刊更多论文

通过二次界面聚合反应制造的高渗透性耐酸聚胺中空纤维纳滤膜

由于在工业废水处理中的应用，耐酸纳滤膜的开发备受关注。在这项工作中，我们利用聚乙烯亚胺（PEI）和氯化氰（CC）在聚醚砜（PES）中空纤维基材上进行了第一次界面聚合（IP）反应，然后利用三（2-氨基乙基）胺（TAEA）进行了二次 IP 处理，与第一次 IP 后残留的氯基发生反应，以提高膜表面的正电荷强度。与第一次 IP 后形成的原始膜相比，TAEA 优化膜的纯水渗透率（PWP）高达 25.2 L m-2 h-1 bar-1，在 2 bar 工作压力下对氯化镁的排斥率接近 90%。同时，在处理合成电镀冲洗水时，该膜在 pH 值为 1 的条件下进行了为期 7 天的运行测试，对 Cu2+ 和 Ni2+ 离子的截留率仍能达到 85%。这些结果证明了该膜在工业酸性废水中去除重金属离子的良好潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Membrane Science 工程技术-高分子科学

CiteScore

17.10

自引率

17.90%

发文量

1031

审稿时长

2.5 months

期刊介绍： The Journal of Membrane Science is a publication that focuses on membrane systems and is aimed at academic and industrial chemists, chemical engineers, materials scientists, and membranologists. It publishes original research and reviews on various aspects of membrane transport, membrane formation/structure, fouling, module/process design, and processes/applications. The journal primarily focuses on the structure, function, and performance of non-biological membranes but also includes papers that relate to biological membranes. The Journal of Membrane Science publishes Full Text Papers, State-of-the-Art Reviews, Letters to the Editor, and Perspectives.