Performance and mechanism of a novel electro-magnetic treatment for improving the cold flowability of waxy crude oil

IF 6.7 1区 工程技术 Q2 ENERGY & FUELS
Fuel Pub Date : 2024-11-23 DOI:10.1016/j.fuel.2024.133803
Yiwei Xie , Hongying Li , Bing Liang , Quande Li , Yang Su , Chaoyue Zhang , Jiabao Kang , Zhaoming Yang , Huai Su , Zhongli Ji , Jinjun Zhang
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Abstract

Under the framework of achieving carbon neutrality, the transformation of pipeline transportation modes, coupled with the poor flowability of crude oil, has raised the standards for ensuring the flow assurance of oil pipelines. Improving the cold flowability of waxy crude oil is crucial for flow assurance. Previous studies have demonstrated that electric or magnetic treatment could have such efficacy. However, the combined treatment of electric and magnetic fields has never been investigated. This paper introduces such a novel exploration, revealing a quite encouraging synergistic effect on cold flowability improvement. Specifically, the crude oil was first exposed to a magnetic field above its WAT, followed by an electric field below the WAT. For the studied crude oil, the synergistic treatment achieved a 50 % reduction in viscosity, compared to 24 % and 30 % reductions for magnetic and electric treatment alone, respectively. Although magnetic treatment showed limited effect on weakening the structural strength of the oil gel, it significantly enhanced the effectiveness of the electric field, increasing the yield stress reduction from 77 % to 84 %. Attention must be paid to the non-monotonic influences of magnetic field strength, treatment duration, and temperature. Mechanistically, magnetic treatment reduced the crude oil’s impedance, indicating an enhanced dispersion of resins and asphaltenes. This improved dispersion allowed for greater adsorption of resins and asphaltenes onto wax particles during subsequent electric treatment, thus making the electric treatment much more effective. These new findings reveal the electro-magnetorheological effects of crude oil, guiding advanced flowability improvement technologies.
用于改善含蜡原油冷流动性的新型电磁处理方法的性能和机理
在实现碳中和的框架下,管道运输模式的转变,加上原油流动性差,提高了确保石油管道流动性的标准。改善含蜡原油的低温流动性是保证流动性的关键。以往的研究表明,电处理或磁处理可以达到这种效果。然而,电场和磁场的组合处理方法还从未被研究过。本文介绍了这一新颖的探索,揭示了在改善冷流动性方面令人鼓舞的协同效应。具体来说,原油首先暴露在高于其加权平均值的磁场中,然后再暴露在低于加权平均值的电场中。对于所研究的原油,协同处理使粘度降低了 50%,而单独使用磁场和电场处理则分别降低了 24% 和 30%。虽然磁处理对削弱油凝胶结构强度的作用有限,但它显著增强了电场的效果,将屈服应力降低率从 77% 提高到 84%。必须注意磁场强度、处理时间和温度的非单调影响。从机理上讲,磁处理降低了原油的阻抗,表明树脂和沥青质的分散性得到了提高。这种分散性的提高使树脂和沥青质在随后的电处理过程中更容易吸附在蜡颗粒上,从而使电处理更加有效。这些新发现揭示了原油的电磁流变效应,为先进的流动性改进技术提供了指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Fuel
Fuel 工程技术-工程:化工
CiteScore
12.80
自引率
20.30%
发文量
3506
审稿时长
64 days
期刊介绍: The exploration of energy sources remains a critical matter of study. For the past nine decades, fuel has consistently held the forefront in primary research efforts within the field of energy science. This area of investigation encompasses a wide range of subjects, with a particular emphasis on emerging concerns like environmental factors and pollution.
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