Smart Metallized Textiles with Emissivity Tuning

Saurabh Khuje, Abdullah Islam, Josephine Soles, Long Zhu and Shenqiang Ren*, 
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Abstract

Smart textiles represent a groundbreaking innovation in integrating advanced sensing capabilities into surfaces previously deemed inaccessible and mark an advancement in the ongoing evolution of highly durable and flexible electronic textiles. The development of e-textiles with electrical circuits capable of withstanding diverse environmental stimuli, alongside repetitive bending and elongation cycles, has remained a critical challenge. In this study, we introduce a transformative approach to versatile sensory e-textiles utilizing a network of copper-coated Kevlar fibers. This approach leverages the synergistic coordination between a printable copper precursor and Kevlar fibers, resulting in robust, long-lasting conductive networks. These networks demonstrate unprecedented long-term cyclability, superior oxidation, and corrosion resistance and maintain stability even in harsh, oxidative environments. Furthermore, they exhibit remarkable washability, ensuring durability in real-world applications. Beyond their durability, these e-textiles perform multifunctional roles, including precise strain sensing and emissivity tuning, achieved through direct current modulation. The strain sensing performance is distinguished by its reliability under repeated 40 wt % stretching cycles. The innovation lies in the multilayered conductive structure, which guarantees continuous percolation, driving enhanced performance in both strain detection and emissivity control. This breakthrough offers a significant leap forward in the development of next-generation smart textiles with wide-ranging applications in wearable electronics, adaptive materials, and beyond.

Abstract Image

具有发射率调节功能的智能金属化纺织品
智能纺织品是一项突破性的创新,它将先进的传感功能集成到以前被认为无法触及的表面,标志着高耐用性和柔韧性电子纺织品的不断发展进步。开发具有电路的电子纺织品,使其能够承受各种环境刺激以及反复的弯曲和拉伸循环,一直是一项严峻的挑战。在本研究中,我们介绍了一种利用铜涂层凯夫拉尔纤维网络开发多功能感知电子织物的变革性方法。这种方法利用了可印刷铜前体与 Kevlar 纤维之间的协同配合,从而形成了坚固耐用的导电网络。这些网络具有前所未有的长期循环性、优异的抗氧化性和耐腐蚀性,即使在恶劣的氧化环境中也能保持稳定。此外,它们还表现出卓越的耐洗性,确保了在实际应用中的耐用性。除了耐用性,这些电子织物还能发挥多功能作用,包括通过直流调制实现精确的应变传感和发射率调节。应变传感性能的显著特点是在 40 wt % 的拉伸循环下仍能保持可靠性。其创新之处在于采用了多层导电结构,保证了连续的渗流,从而提高了应变检测和发射率控制的性能。这一突破为下一代智能纺织品的开发带来了重大飞跃,可广泛应用于可穿戴电子产品、自适应材料等领域。
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期刊介绍: ACS Applied Engineering Materials is an international and interdisciplinary forum devoted to original research covering all aspects of engineered materials complementing the ACS Applied Materials portfolio. Papers that describe theory simulation modeling or machine learning assisted design of materials and that provide new insights into engineering applications are welcomed. The journal also considers experimental research that includes novel methods of preparing characterizing and evaluating new materials designed for timely applications. With its focus on innovative applications ACS Applied Engineering Materials also complements and expands the scope of existing ACS publications that focus on materials science discovery including Biomacromolecules Chemistry of Materials Crystal Growth & Design Industrial & Engineering Chemistry Research Inorganic Chemistry Langmuir and Macromolecules.The scope of ACS Applied Engineering Materials includes high quality research of an applied nature that integrates knowledge in materials science engineering physics mechanics and chemistry.
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