Synthesis and Reactivity of Palladium Complexes Bearing Phosphino-Amidinate Ligands: O–H Bond Activation by Metal–Ligand Cooperation

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2024-11-13 DOI:10.1021/acs.organomet.4c0042910.1021/acs.organomet.4c00429

Yuka Yamamoto, Tomoya Mommae, Tatsuya Fujimoto, Mitsuru Kondo and Naofumi Tsukada*,

引用次数: 0

Abstract

Phosphine ligands bearing amidine groups were designed for the synthesis of complexes in which a metal center and ligands cooperate. Several palladium amidinate complexes were synthesized from these ligands. The reaction of these complexes with various organic molecules containing an acidic OH group gave the palladium amidine complexes. In the reaction, the O–H bond was activated by metal–ligand cooperation (MLC).

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膦脒配体钯配合物的合成与反应活性：金属配体合作激活 O-H 键

为了合成金属中心与配体合作的配合物，我们设计了带有脒基的膦配体。利用这些配体合成了几种脒基钯配合物。这些络合物与含有酸性羟基的各种有机分子反应后，得到了钯脒络合物。在反应过程中，O-H 键被金属配体合作（MLC）激活。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.