Fundamentals of metal-organic framework-based photocatalysts: The role of chemical diversity and structure engineering

IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Qi Ran , Binbin Tao , Mohua Li , Kaidan Zheng , Yunyong She , Wenjie Wu , Zhengtong Li , Dan Luo , Xingtao Xu
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引用次数: 0

Abstract

The utilization of solar energy in driving chemical reactions through photocatalysis is essential in promoting a sustainable future. However, the development of synthetic materials with photochemical properties continues to pose a significant challenge in the field of materials science. Metal-organic frameworks (MOFs) provide a powerful platform for establishing effective photocatalyst systems due to their atomically precise structures, modifiable chemical environment, and semiconductor-like behavior. This work comprehensively reviews the design and synthesis strategies of MOF-based photocatalysts, with particular emphasis on light absorption, photogenerated carrier separation, catalytic active sites, and reaction selectivity. The objective of these approaches is to identify and rationalize design parameters to generate optimized chemical composition, functional nanostructures, and corresponding performance parameters. In this review, we highlight how the parameters of MOFs can serve as the knobs for maneuvering light harvesting, charge separation and migration, as well as altering subsequent surface chemical reaction. We hope that this will contribute towards further understanding and inspiration for developing photocatalytic reaction based on MOFs materials.

Abstract Image

Abstract Image

基于金属有机框架的光催化剂的基本原理:化学多样性和结构工程的作用
通过光催化利用太阳能推动化学反应,对促进可持续发展的未来至关重要。然而,开发具有光化学特性的合成材料仍然是材料科学领域的一项重大挑战。金属有机框架(MOFs)因其精确的原子结构、可改变的化学环境和类似半导体的行为,为建立有效的光催化剂系统提供了一个强大的平台。本研究全面回顾了基于 MOF 的光催化剂的设计和合成策略,特别强调了光吸收、光生载流子分离、催化活性位点和反应选择性。这些方法的目的是确定并合理调整设计参数,以产生优化的化学成分、功能纳米结构和相应的性能参数。在本综述中,我们将重点介绍 MOFs 的参数如何作为操纵光采集、电荷分离和迁移以及改变后续表面化学反应的旋钮。我们希望这将有助于进一步理解和启发开发基于 MOFs 材料的光催化反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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