Enhanced C3H6/C3H8 separation performance in polysulfone membrane blended with rigid ZIF-8 crystals

IF 4.3 3区工程技术 Q2 ENGINEERING, CHEMICAL

Frontiers of Chemical Science and Engineering Pub Date : 2024-09-15 DOI:10.1007/s11705-024-2504-3

Jiayu Luo, Luxi Lyu, Zongjie Yin, Yanying Wei

{"title":"Enhanced C3H6/C3H8 separation performance in polysulfone membrane blended with rigid ZIF-8 crystals","authors":"Jiayu Luo, Luxi Lyu, Zongjie Yin, Yanying Wei","doi":"10.1007/s11705-024-2504-3","DOIUrl":null,"url":null,"abstract":"<div><p>Metal-organic frameworks have a wide range of applications in the field of membrane separation, but the inherent flexible structure and the difficulty for scale-up hinder their further applications. Herein, the relatively rigid zeolitic imidazolate framework-8 particles prepared under an electric field (E-ZIF-8) were used as the fillers in polysulfone (PSF) to form series of mixed matrix membranes. It was found that the introduction of E-ZIF-8 improves both the C<sub>3</sub>H<sub>6</sub> permeability and C<sub>3</sub>H<sub>6</sub>/C<sub>3</sub>H<sub>8</sub> selectivity of the membranes. Compared with the bare PSF membrane, the C<sub>3</sub>H<sub>6</sub>/C<sub>3</sub>H<sub>8</sub> selectivity of the 30 wt % E-ZIF-8@PSF membrane increased by ∼230%, while the C<sub>3</sub>H<sub>6</sub> permeability was enhanced by ∼830%. In addition, time and pressure dependence analysis demonstrated that such E-ZIF-8@PSF membranes also exhibited good long-term stability and pressure resistance, offering significant industrialization advantages.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-024-2504-3","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Metal-organic frameworks have a wide range of applications in the field of membrane separation, but the inherent flexible structure and the difficulty for scale-up hinder their further applications. Herein, the relatively rigid zeolitic imidazolate framework-8 particles prepared under an electric field (E-ZIF-8) were used as the fillers in polysulfone (PSF) to form series of mixed matrix membranes. It was found that the introduction of E-ZIF-8 improves both the C₃H₆ permeability and C₃H₆/C₃H₈ selectivity of the membranes. Compared with the bare PSF membrane, the C₃H₆/C₃H₈ selectivity of the 30 wt % E-ZIF-8@PSF membrane increased by ∼230%, while the C₃H₆ permeability was enhanced by ∼830%. In addition, time and pressure dependence analysis demonstrated that such E-ZIF-8@PSF membranes also exhibited good long-term stability and pressure resistance, offering significant industrialization advantages.

查看原文本刊更多论文

增强聚砜膜与硬质 ZIF-8 结晶体的 C3H6/C3H8 分离性能

金属有机框架在膜分离领域有着广泛的应用，但其固有的柔性结构和放大困难阻碍了其进一步应用。在此，我们使用在电场下制备的相对坚硬的沸石咪唑盐酸盐框架-8 颗粒（E-ZIF-8）作为聚砜（PSF）的填料，形成了一系列混合基质膜。研究发现，E-ZIF-8 的引入提高了膜的 C3H6 渗透性和 C3H6/C3H8 选择性。与裸 PSF 膜相比，30 wt % E-ZIF-8@PSF 膜的 C3H6/C3H8 选择性提高了 ∼230%，而 C3H6 渗透性提高了 ∼830%。此外，时间和压力依赖性分析表明，这种 E-ZIF-8@PSF 膜还具有良好的长期稳定性和耐压性，具有显著的工业化优势。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Frontiers of Chemical Science and Engineering ENGINEERING, CHEMICAL-

CiteScore

7.60

自引率

6.70%

发文量

868

审稿时长

1 months

期刊介绍： Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.