{"title":"Dual-Gas Coproduction via Depressurization for Methane Hydrate Under Semiadiabatic Heat Transfer Boundary Conditions","authors":"Xian Sun, Yu-Zhou Chen, Xiao-Hui Wang*, Yi-Fei Sun, Xing-Xun Li, Peng Xiao, Qing-Ping Li, Chang-Yu Sun* and Guang-Jin Chen, ","doi":"10.1021/acs.energyfuels.4c0406810.1021/acs.energyfuels.4c04068","DOIUrl":null,"url":null,"abstract":"<p >This study simulates constrained heat transfer processes in natural environments by establishing a semiadiabatic boundary during methane hydrate formation and dissociation, utilizing an apparatus insulated with materials of low thermal conductivity. Within this semiadiabatic framework, the decrease in system temperature induced by heat absorption during hydrate decomposition cannot be promptly compensated by external heat sources. These results in reduced gas production rates and a lower proportion of gas deriving from hydrate dissociation compared to that observed with an isothermal boundary. The proportion of gas from hydrate dissociation in the produced gas in the semiadiabatic system was lower than that in the isothermal boundary, especially in the early and middle stages. The observed differences in hydrate dissociation behaviors between semiadiabatic and isothermal conditions provide critical insights into the interpretation of experimental studies and their applicability to natural hydrate reservoirs. These findings suggest implications for translating laboratory results into practical strategies for the exploitation of hydrate resources.</p>","PeriodicalId":35,"journal":{"name":"Energy & Fuels","volume":"38 22","pages":"22146–22160 22146–22160"},"PeriodicalIF":5.3000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Fuels","FirstCategoryId":"5","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.energyfuels.4c04068","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
This study simulates constrained heat transfer processes in natural environments by establishing a semiadiabatic boundary during methane hydrate formation and dissociation, utilizing an apparatus insulated with materials of low thermal conductivity. Within this semiadiabatic framework, the decrease in system temperature induced by heat absorption during hydrate decomposition cannot be promptly compensated by external heat sources. These results in reduced gas production rates and a lower proportion of gas deriving from hydrate dissociation compared to that observed with an isothermal boundary. The proportion of gas from hydrate dissociation in the produced gas in the semiadiabatic system was lower than that in the isothermal boundary, especially in the early and middle stages. The observed differences in hydrate dissociation behaviors between semiadiabatic and isothermal conditions provide critical insights into the interpretation of experimental studies and their applicability to natural hydrate reservoirs. These findings suggest implications for translating laboratory results into practical strategies for the exploitation of hydrate resources.
期刊介绍:
Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.