Zhiqiang Yang , Xin Wang , Bolong Hong , Kesheng Gao , Na Li , Lei Gao , Kang Wu , Jinlong Zhu , Enyue Zhao , Songbai Han
{"title":"Anomalous stable 4.6 V LiCoO2 in all-solid-state lithium batteries","authors":"Zhiqiang Yang , Xin Wang , Bolong Hong , Kesheng Gao , Na Li , Lei Gao , Kang Wu , Jinlong Zhu , Enyue Zhao , Songbai Han","doi":"10.1016/j.nanoen.2024.110495","DOIUrl":null,"url":null,"abstract":"<div><div>The commercialization of high-voltage LiCoO<sub>2</sub> (LCO) which possesses ultrahigh volumetric energy density is largely limited by a rapid capacity degradation. Although much progress has been made in optimizing high-voltage LCO, the long-cycled irreversible structure transformation and capacity loss is not practically solved, meaning that there are still scientific questions to be answered. Here, we report an anomalous stable 4.6 V (vs. Li/Li<sup>+</sup>) LCO with a record long-cycle capacity retention (94 % after 200 cycles at 2 C) in an all-solid-state lithium battery (ASSLB) system, which rarely achieved in the liquid one. The stable 4.6 V LCO originates from the unique ionic diffusion environment in the ASSLB, unlike in the liquid one, where there is a similar Li-ion diffusion velocity between the LCO’s bulk and surface structure. Such a homogenous bulk-to-surface Li concentration distribution upon cycling can well retard the irreversible phase transitions, as directly revealed by transmission electron microscopy. More broadly, this work unlocks the role of cycled Li distribution, a previously un-answered scientific question, in optimizing high-voltage Li-storage lattice and also sheds light on the design of high-voltage ASSLBs.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"133 ","pages":"Article 110495"},"PeriodicalIF":16.8000,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Energy","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211285524012473","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The commercialization of high-voltage LiCoO2 (LCO) which possesses ultrahigh volumetric energy density is largely limited by a rapid capacity degradation. Although much progress has been made in optimizing high-voltage LCO, the long-cycled irreversible structure transformation and capacity loss is not practically solved, meaning that there are still scientific questions to be answered. Here, we report an anomalous stable 4.6 V (vs. Li/Li+) LCO with a record long-cycle capacity retention (94 % after 200 cycles at 2 C) in an all-solid-state lithium battery (ASSLB) system, which rarely achieved in the liquid one. The stable 4.6 V LCO originates from the unique ionic diffusion environment in the ASSLB, unlike in the liquid one, where there is a similar Li-ion diffusion velocity between the LCO’s bulk and surface structure. Such a homogenous bulk-to-surface Li concentration distribution upon cycling can well retard the irreversible phase transitions, as directly revealed by transmission electron microscopy. More broadly, this work unlocks the role of cycled Li distribution, a previously un-answered scientific question, in optimizing high-voltage Li-storage lattice and also sheds light on the design of high-voltage ASSLBs.
期刊介绍:
Nano Energy is a multidisciplinary, rapid-publication forum of original peer-reviewed contributions on the science and engineering of nanomaterials and nanodevices used in all forms of energy harvesting, conversion, storage, utilization and policy. Through its mixture of articles, reviews, communications, research news, and information on key developments, Nano Energy provides a comprehensive coverage of this exciting and dynamic field which joins nanoscience and nanotechnology with energy science. The journal is relevant to all those who are interested in nanomaterials solutions to the energy problem.
Nano Energy publishes original experimental and theoretical research on all aspects of energy-related research which utilizes nanomaterials and nanotechnology. Manuscripts of four types are considered: review articles which inform readers of the latest research and advances in energy science; rapid communications which feature exciting research breakthroughs in the field; full-length articles which report comprehensive research developments; and news and opinions which comment on topical issues or express views on the developments in related fields.