Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core – a donor–acceptor multi-redox system†

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-09-02 DOI:10.1039/d4ob01755b

Jeppe Granhøj , Viktor Bliksted Roug Pedersen , Kurt V. Mikkelsen , Mogens Brøndsted Nielsen

引用次数: 0

Abstract

A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

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具有五烯并[1,2-b:4,5-b']二芴核心的扩展四硫杂戊烯--一种供体-受体多重氧化还原系统。

通过引入大的五烯并[1,2-b:4,5-b']二芴作为中心多环芳烃分子，制备出了一种新型的扩展四硫富戊烯。该化合物是一个多氧化还原体系，可以可逆地呈现六种氧化还原状态（-1、0、+1、+2、+3、+4）。该化合物在可见光区域表现出很强的吸收能力，其末端吸收几乎达到 700 纳米。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.