A comprehensive review of cellulose nanomaterials for adsorption of wastewater pollutants: focus on dye and heavy metal Cr adsorption and oil/water separation

Yadong Yang, Xuanze Li, Caichao Wan, Zhe Zhang, Wenzhe Cao, Guanyu Wang, Yiqiang Wu
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Abstract

Cellulose is widely distributed in higher plants and constitutes the most abundant natural biopolymer on Earth. Nanocellulose is a cellulose material with nanoscale dimensions, obtained through special processing and treatment. Up to now, nanocellulose has been widely investigated as a biosorbent to absorb various types of pollutants in wastewater due to its excellent properties, such as large specific surface area, antifouling behaviour, high aspect ratio, high heat resistance, excellent mechanical properties, biodegradability and biocompatibility. In addition, nanocellulose can be rationally structured by different recombination techniques such as membranes, sponges, aerogels, hydrogels and microspheres and provide specialised functionality for the adsorption of various types of pollutants from wastewater. This review introduces the basic properties, classification and modification methods of nanocellulose; discusses the preparation strategies of nanocellulose-based recombinant materials (including vacuum/pressurised filtration, sol–gel and electrospinning); reviews research progress in the adsorption of organic dyes and heavy metal Cr, as well as the separation of oil/water using nanocellulose-based recombinant materials; and explores the potential of nanocellulose in treating tannery wastewater. Finally, the problems faced by nanocellulose-based recombinant materials and future prospects are presented.

Graphical Abstract

全面评述用于吸附废水污染物的纤维素纳米材料:重点关注染料和重金属 Cr 的吸附以及油/水分离
纤维素广泛分布于高等植物中,是地球上最丰富的天然生物聚合物。纳米纤维素是一种通过特殊加工和处理获得的具有纳米尺寸的纤维素材料。纳米纤维素具有比表面积大、防污、高纵横比、高耐热性、优异的机械性能、生物可降解性和生物相容性等优良特性,迄今为止,纳米纤维素作为一种生物吸附剂吸收废水中的各种污染物已得到广泛研究。此外,纳米纤维素还可以通过不同的重组技术(如膜、海绵、气凝胶、水凝胶和微球)进行合理的结构化,并为吸附废水中的各类污染物提供专门的功能。本综述介绍了纳米纤维素的基本特性、分类和改性方法;讨论了基于纳米纤维素的重组材料的制备策略(包括真空/加压过滤、溶胶-凝胶和电纺丝);回顾了利用基于纳米纤维素的重组材料吸附有机染料和重金属 Cr 以及分离油/水的研究进展;并探讨了纳米纤维素在处理制革废水方面的潜力。最后,介绍了基于纳米纤维素的重组材料面临的问题和未来前景。 图文摘要
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Leather Science and Engineering
Journal of Leather Science and Engineering 工程技术-材料科学:综合
CiteScore
12.80
自引率
0.00%
发文量
29
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