Dual-mode Luminescence and Anti-counterfeiting Application of YVO4: Eu3+@SiO2@CDs Nanocomposites

Abstract

With the combination of carbon quantum dots (CDs) and rare earth-doped fluorescent materials, multi-mode luminescence can be achieved in fluorescent ink, thereby enhancing its anti-counterfeiting security coefficient. However, the self-quenching process in CDs currently hinders their application in the field of anti-counterfeiting. In this study, we employed simple chemical method to prepare the SiO₂-encapsulated YVO₄:Eu³⁺/CDs nanocomposites, which greatly improved the stability of the composite and achieved dual-mode solid-state luminescence. Quick response code anti-counterfeiting patterns were fabricated using screen printing technology, and dual-mode luminescence performance with red and blue emission was achieved under excitation at 254 nm and 365 nm respectively. The YVO₄:Eu³⁺@SiO₂@CDs nanocomposites showed stable dual-mode luminescent performance in both solid-state and solvent environment, demonstrating great potential in anticounterfeiting and information protection application.