Front Cover: Luminescence and Single-Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near-Planar Tricoordinate Ytterbium(III) Amide (ChemistryEurope 6/2024)
Dr. Nimisha Jain, Dr. Félix Houard, Rémi Marchal, Marie Cordier, Dr. Boris Le Guennic, Dr. Yan Suffren, Dr. Yann Sarazin, Prof. Kevin Bernot
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Abstract
The Front Cover shows a magnetic molecule that is being considered for nanoscale information storage and quantum applications. An ideal molecule based on a tri-coordinated YbIII was theorised in 2021. In their Research Article (DOI: 10.1002/ceur.202400062), Y. Sarazin, K. Bernot and co-workers show that this molecule does indeed possess the ideal electronic structure postulated, but that its performance is much weaker than expected. The anomalies observed in its infrared emission could be an experimental signature of active vibronic contributions in the molecule, detrimental to its magnetic behaviour.
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