Fabrication of polydopamine doped helical/chiral porous carbon fiber (HPCFs@PDA) and N-doped carbon layers (HPCFs@NCLs) for their application as wave absorber with ultrawide EAB

Abstract

A new class of wave absorbing materials HPCFs_t@PDA and HPCFs_t@NCLs (where HPCFs describes helical/chiral porous carbon fiber, t refers to carbonization 700, 800 °C, PDA ascribed to poly (dopamine), and NCLs corresponds to nitrogen doped carbon layers) with helical/chiral, hierarchical, multi-layered structural morphology containing different heterostructures was triumphantly constructed through single-step carbonization of HPCFs_t. The HPCFs_t biomass fiber was go through self-polymerization of dopamine and we get HPCFs₇₀₀@PDA, HPCFs₈₀₀@PDA as an intermediate product. Finally, the PDA doped HPCFs biomass (HPCFs₇₀₀@PDA, HPCFs₈₀₀@PDA) was effectively transformed into NCLs from inside toward outside (HPCFs₇₀₀@NCLs, HPCFs₈₀₀@NCLs) through carbonization. Notably, HPCFs exhibit helical/chiral, hierarchical porous morphology with hetero-interfaces (such as dipole interfaces) that improve dielectric loss, while PDA and NCLs ameliorate wave absorber conductivity, through generation of polarization centers, heterointerfaces and resulting in considerable dielectric loss. Moreover, HPCFs with such unique structural morphology provide additional loss mechanism through cross-polarization that improve dissipation/attenuation of microwave. The microwave absorption mechanism of HPCFs_t@PDA_(1–3), HPCFs_t@NCLs_(1–3) (where 1, 2, 3 refer to filler content 27.50, 30.00, 32.50%wt PDA derived absorber and 20.00, 22.50, 25.00%wt NCLs filler) and their structure active relationship are further elucidated. Evidently, HPCFs₇₀₀@PDA₂ gained reflection loss (RL) of −51.60 dB at 13.60 GHz, across the broad spectrum of frequencies (EAB, RL ≤ −10 dB) covers 6.70 GHz (11.30–18.00 GHz) at 2.70 mm thickness. The EAB ameliorate to the value of 7.20 GHz (10.70–18.00 GHz) at thickness of 2.80 mm. While HPCFs₇₀₀@NCLs₂ RL was improved to −63.00 dB at 2.40 mm thickness with EAB 5.10 GHz (11.40–16.50) at 13.30 GHz frequency. Likewise, HPCFs₈₀₀@PDA₂ RL elevates to the value of −53.40 dB with adequate EAB covering 12.80–18.00 GHz (5.20 GHz) at higher values of 14.40 GHz and 2.10 mm thickness. For HPCFs₈₀₀@NCLs₂, the RL is as high as −65.40 dB at 9.90 GHz, with an effective thickness of 3.20 mm covering 7.50–11.20 GHz (3.20 GHz) EAB. At matching thickness of 2.00 mm the EAB covers 13.80–18.00 (4.20 GHz). Their top-notch microwave absorption capabilities with widened EAB at lower matching thickness demonstrate potentially promising prospects of HPCFs_t@PDA and HPCFs_t@NCLs as wave absorbing materials.