Dongpu Wu, Zheng Yang, Yuchen Xia, Lulu Wu, Yingxia Zhou, Caoyuan Niu, Puhui Xie, Xin Zheng, Zhanqi Cao
{"title":"Surface controllable wettability using amphiphilic rotaxane molecular shuttles","authors":"Dongpu Wu, Zheng Yang, Yuchen Xia, Lulu Wu, Yingxia Zhou, Caoyuan Niu, Puhui Xie, Xin Zheng, Zhanqi Cao","doi":"10.1016/j.cclet.2024.110353","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, an alkyne-terminated acid/base responsive amphiphilic [2]rotaxane shuttle was synthesized, and then modified onto the glass surface through “click” reaction. The XPS N 1s spectrum and contact-angle measurement were performed to prove the successful immobilization. The amphiphilic [2]rotaxane functionalized surface presented controllable wettability responding to external acid-base stimuli. This bistable rotaxane modified material system promoted the practical application of molecular machines.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110353"},"PeriodicalIF":9.4000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Chemical Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1001841724008726","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Herein, an alkyne-terminated acid/base responsive amphiphilic [2]rotaxane shuttle was synthesized, and then modified onto the glass surface through “click” reaction. The XPS N 1s spectrum and contact-angle measurement were performed to prove the successful immobilization. The amphiphilic [2]rotaxane functionalized surface presented controllable wettability responding to external acid-base stimuli. This bistable rotaxane modified material system promoted the practical application of molecular machines.
期刊介绍:
Chinese Chemical Letters (CCL) (ISSN 1001-8417) was founded in July 1990. The journal publishes preliminary accounts in the whole field of chemistry, including inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry, polymer chemistry, applied chemistry, etc.Chinese Chemical Letters does not accept articles previously published or scheduled to be published. To verify originality, your article may be checked by the originality detection service CrossCheck.